MATHESON TRI-GAS, INC. -- CUMENE -- -
===================== Product Identification ===================== Product ID:CUMENE MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:CUMENE CAS:98-82-8 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: irritation, nausea, difficulty breathing, headache, symptoms of drunkenness LONG TERM EXPOSURE: no information on significant adverse effects SKIN CONTACT: SHORT TERM EXPOSURE: irritation, blisters, symptoms of drunkenness LONG TERM EXPOSURE: rash, itching EYE CONTACT: SHORT TERM EXPOSURE: irritation, tearing LONG TERM EXPOSURE: same as effects reported in short term exposure INGESTION: SHORT TERM EXPOSURE: vomiting, stomach pain, symptoms of drunkenness, lung congestion LONG TERM EXPOSURE: no information on significant adverse effects Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. NOTE TO PHYSICIAN: For ingestion, consider gastric lavage. ===================== Fire Fighting Measures ===================== Flash Point:97 F (36 C) (CC) Autoignition Temp:795 F (424 C) Lower Limits:0.9% Upper Limits:6.5% Extinguishing Media:regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material ocombustion by-products. Stay upwind and keep out of low areas. Unusual Fire/Explosion Hazard:Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. Electrostatic discharges may be generated by flow or agitation resulting in ignition or explosion. ================== Accidental Release Measures ================== Spill Release Procedures:[Spills may need to be reported to the National Response Center (800/424-8802) CERCLA Reportable Quantity (RQ) is 1000 pounds]. Shut off and eliminate all ignition sources. Keep people away. Recover by pumping (use an explosion proof or hand pump) or with a suitable absorbent such as sand, earth or other suitable absorbent to spill area. Do not use combustible materials such as sawdust. Minimize breathing vapors. Minimize skin contact. Ventilate confined spaces. Open all windows and doors. Keep product out of sewers and watercourses by diking or impounding. Advise authorities if product has entered or may enter sewers, watercourses, or extensive land areas. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Keep away from heat, sparks and open flames. Keep containers tightly closed. Store away from strong oxidizing agents in a cool, dry place with adequate explosion-proof ventilation. Ground equipment to prevent accumulation of static charge. If pouring or transferring materials, containers must be bonded and grounded. Other Precautions:Do Not weld, heat or drill on or near container; even emptied containers can contain explosive vapors. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 500 ppm Any chemical cartridge respirator with organic vapor cartridge(s). Any supplied-air respirator. 900 ppm Any supplied-air respirator. Any powered, air-purifying respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. Escape - Any air-purifying respirator with a full facepiece and an organic vapor canister. Any appropriate escape-type, self-contained breathing apparatus. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust or process enclosure ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health CUMENE: 50 ppm (245 mg/m3) OSHA TWA (skin) 50 ppm ACGIH TWA 50 ppm (245 mg/m3) NIOSH recommended TWA 10 hour(s) (skin) ================== Physical/Chemical Properties ================== Boiling Pt:306 F (152 C) Melt/Freeze Pt:-141 F (-96 C) Vapor Pres:8 mmHg @ 20 C Vapor Density:4.1 Spec Gravity:0.86 pH:Not available Evaporation Rate & Reference:Not available Solubility in Water:insoluble Appearance and Odor:PHYSICAL STATE:liquid COLOR:colorless ODOR:distinct odor, pungent odor Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stable at normal temperatures and pressure. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers. Hazardous Decomposition Products:Thermal decomposition products: oxides of carbon Thermal decomposition products: oxides of carbon Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:CUMENE: IRRITATION DATA: 10 mg/24 hour(s) open skin-rabbit mild; 100 mg/24 hour(s) skin-rabbit moderate; 86 mg eyes-rabbit mild; 500 mg/24 hour(s) eyes-rabbit mild TOXICITY DATA: 10 gm/m3/7 hour(s) inhalation-mouse LC50; 12300 ul/kg skin-rabbit LD50; 1400 mg/kg oral-rat LD50 LOCAL EFFECTS: Irritant: skin ACUTE TOXICITY LEVEL: Moderately Toxic: inhalation, ingestion Slightly Toxic: dermal absorption TARGET ORGANS: central nervous system MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: liver and/or kidney disorders, liver disorders, respiratory disorders, skin disorders and allergies ADDITIONAL DATA: Alcohol may enhance the toxic effects. Stimulants such as epinephrine may induce ventricular fibrillation. ===================== Ecological Information ===================== Ecological:ECOTOXICITY DATA: FISH TOXICITY: 5100 ug/L 96 hour(s) LC50 (Mortality) Guppy (Poecilia reticulata) INVERTEBRATE TOXICITY: 100 mg/L 24 hour(s) EC100 (Abundance) Water flea (Daphnia magna) ALGAL TOXICITY: 2600 ug/L 72 hour(s) EC50 (Growth) Green algae (Selenastrum capricornutum) ==================== Disposal Considerations ==================== Waste Disposal Methods:Use non-leaking containers, seal tightly and label properly. Dispose of in accordance with applicable local, county, state and federal regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Isopropenylbenzene ID NUMBER: UN2303 HAZARD CLASS OR DIVISION: 3 PACKING GROUP: III LABELING REQUIREMENTS: Flammable liquid ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40 CFR 372.65): CUMENE Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): CUMENE: 5000LBSRQ OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.