ALDON CORP. -- FORMIC ACID -- -
===================== Product Identification ===================== Product ID:FORMIC ACID MSDS Date:06/04/1996 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:ALDON CORP. Address:1533 W HENRIETTA RD City:AVON State:NY ZIP:14414 Country:US Info Phone Num:716-226-6177 Emergency Phone Num:716-226-6177 Resp. Party Other MSDS Num.:FF 270 Preparer's Name:MICHAEL RASZEJA Chemtrec Ind/Phone:(800)424-9300 CAGE:6V042 === Contractor Identification === Company Name:AL-DON CHEMICALS INC Address:1533 W HENRIETTA RD Box:City:AVON State:NY ZIP:14414-9508 Country:US Phone:716-226-6177 CAGE:6V042 Company Name:CENTRAL SCIENTIFIC CO Address:3300 CENCO PKY Box:City:FRANKLIN PARK State:IL ZIP:60131-1364 Country:US Phone:847-451-0150 Contract Num:MDA414-99-P-4954 CAGE:0ZGA2 ============= Composition/Information on Ingredients ============= Ingred Name:FORMIC ACID CAS:64-18-6 RTECS #:LQ4900000 Minumum % Wt:88. Maxumum % Wt:90. OSHA PEL:9 MG/M3;5 PPM ACGIH TLV:9.4 MG/M3;5 PPM ACGIH STEL:19 MG/M3;10 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): UNKNOWN. Health Hazards Acute and Chronic:FORMIC ACID IS A HIGHLY TOXIC SUBSTANCE WHICH ALSO HAS CORROSIVE ACTION ON ANY BODY TISSUE IT CONTACTS. EYE: WITH LIQUID OR HIGH VAPOR CONCENTRATIONS WILL PRODUCE IRRITATION AND CONJUNCTIVITIS AND MAY CAUSE CORNEAL BURNS. ISKIN: CONTACT WILL CAUSE IRRITATION AND BURNS. NHALATION: EXCESSIVE INHALATION OF VAPORS IS IRRITATING TO UPPER RESPIRATORY TRACT. INGESTION: CAUSES ACUTE LOCAL TISSUE DAMAGE WI TH OTHER EFFECTS RANGING FROM NAUSEA AND DIZINESS TO UNCONSCIOUSNESS. Effects of Overexposure:EYE-CORNEAL BURNS. SKIN-BURNS. INGESTION-NAUSEA, DIZZINESS, UNCONSCIOUSNESS. Medical Cond Aggravated by Exposure:NONE SPECIFIED ======================= First Aid Measures ======================= First Aid:EYES-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES INCLUDING UNDER EYELIDS. GET IMMEDIATE MEDICAL ATTENTION. SKIN-FLUSH WITH WATER, THEN WASH WITH SOAP AND WATER. GET MEDICAL ATTENTIO N IF IRRITATION PERSISTS. INHALATION-REMOVE TO FRESH AIR. IF ILLNESS OR DISCOMFORT DEVELOPS, GET MEDICAL ATTENTION. INGESTION-IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE 1-2 GLASSES OF MI LK OR WATER TO DRINK. CALL A PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:=71.C, 159.8F Autoignition Temp:=600.C, 1112.F Lower Limits:18% Upper Limits:57% Extinguishing Media:CARBON DIOXIDE(CO2); DRY CHEMICAL (ABC); WATER SPRAY Fire Fighting Procedures:THIS COMBUSTIBLE MATERIAL IS A MODERATE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. FIREFIGHTERS MUST USE EYE PROTECTION AND SELF-CONTAINED BREATHING EQUIPMENT WITH FULL PROTECTIVE CLOTHING TO FIGHT FI RES IN WHICH THIS MATERIAL IS INVOLVED. Unusual Fire/Explosion Hazard:CORROSIVE FUMES. DANGEROUSLY CAUSTIC TO SKIN. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS; CAN REACT VIGOROUSLY WITH OXIDIZING MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE MAXIMUM VENTILATION AND ELIMINATE IGNITION SOURCES.ABSORB SPILL IN VERMICULITE, SAND, EARTH, PAPER TOWEL AND PLACE IN SUITABLE CONTAINER FOR DISPOSAL. NEUTRALIZE REMAINING TRACES OF RESIDUE WI TH SODA ASH AND FLUSH TO DRAIN WITH LARGE AMOUNTS OF WATER. Neutralizing Agent:SODA ASH ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM STRONG OXIDIZERS AND FIRE HAZARDS. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:READ LABEL ON CONTAINER BEFORE USE. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. AVOID BREATHING VAPORS. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN, EYES, CLOTHING. REMOVE ALL C ONTAMINATED CLOTHING AND SHOES AT ONCE. WASH BEFORE REUSING. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WORK IN A FUME HOOD OR WEAR A N IOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR. Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL): RECOMMENDED Protective Gloves:RUBBER Eye Protection:GOGGLES Other Protective Equipment:SMOCK, APRON, CHEMICAL SAFETY GLASSES, EYE WASH STATION, VENTILATION HOOD, PROPER GLOVES, FIRE EXTINGUISHER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.AVOID BREATHING VAPORS. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN, EYES,CLOTHING. REMOVE ALL CONTAMINATED CLOTHING AND SHOES AT ONCE.WASH BEFORE REUSING. Supplemental Safety and Health OTHER PRECAUTIONS: FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD OR HOUSEHOLD USE. KEEP OUT OF REACH OF CHILDREN. *******CENCO P/N: 37054-10. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:=101.C, 213.8F Melt/Freeze Pt:=8.C, 46.4F Vapor Pres:23MM Vapor Density:1.59 Spec Gravity:1.213 Evaporation Rate & Reference:>1(BUAC=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR,COLORLESS FUMING LIQUID;PUNGENT PENETRATING ODOR. Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIES, STRONG OXIDIZERS ,CONCENTRATED SULFURIC ACID. Stability Condition to Avoid:EXCESSIVE TEMPERATUR AND HEAT. Hazardous Decomposition Products:THERMAL DECOMPOSITION OR BURNING MAY PRODUCE CARBON DIOXIDE AND/OR CARBON MONOXIDE. =================== Toxicological Information =================== Toxicological Information:STEL: 10 PPM, 19 MG/M3; TWA: 5 PPM; 9.4 MG/M3 (AIR). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS. THESE DISPOSAL GUIDE LINES ARE INTENDED FOR CATALOG-SIZE QUANTITIES ONLY. DISPOSE OF IN AN APPROVED INCINERATOR EQUIPP ED WITH AN AFTERBURNER AND SCRUBBER. =================== MSDS Transport Information =================== Transport Information:D.O.T.: FORMIC ACID, 8, UN1779, PG II. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.