PHOENIX INDUSTRIES INC -- BUTOXYETHANOL, TECHNICAL -- 6810-00-281-2001
===================== Product Identification ===================== Product ID:BUTOXYETHANOL, TECHNICAL MSDS Date:04/06/1999 FSC:6810 NIIN:00-281-2001 Status Code:A === Responsible Party === Company Name:PHOENIX INDUSTRIES INC Address:11028 LEADBETTER RD UNIT 10 City:ASHLAND State:VA ZIP:23005 Country:US Info Phone Num:804-264-5183 Emergency Phone Num:(800)424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:0YED2 === Contractor Identification === Company Name:PHOENIX INDUSTRIES INC Address:1519 CHAMBERLAYNE PARKWAY Box:City:RICHMOND State:VA ZIP:23222 Country:US Phone:804-264-5183/FAX: 264-5535 Contract Num:SP0450-99-M-C962 CAGE:0YED2 Company Name:PHOENIX INDUSTRIES INC Address:1519 CHAMBERLAYNE PARKWAY Box:City:RICHMOND State:VA ZIP:23222 Country:US Phone:804-264-5183/FAX: 264-5535 Contract Num:SP0450-99-M-NF14 CAGE:0YED2 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Minumum % Wt:99. Maxumum % Wt:100. OSHA PEL:240 MG/M3;50 PPM ACGIH TLV:121 MG/M3;25 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 470 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: LIVER, KIDNEYS, LYMPHOID SYSTEM, BLOOD AND BLOOD-FORMING ORGANS. ACUTE: INHALATION CAUSES IRRITATION TO THE RESPIRATORY TRACT. INGESTION CAUSES IRRITATION TO THE GASTROINTESTINAL TRACT . SKIN CONTACT MAY CAUSE IRRITATION WITHREDNESS & PAIN. MAY BE ABSORBED THROUGH SKIN WITH POSSIBLE SYSTEMIC EFFECTS. EYE CONTACT WITH VAPORS ARE IRRITATING. SPLASHES CAN CAUSE SEVERE PAIN, STINGING, S WELLING. CHRONIC: PROLONGED OR REPEATED EXPOSURES CAN CAUSE DAMAGE TO THE LIVER, KIDNEYS, LYMPHOID SYSTEM, BLOOD AND BLOOD-FORMING ORGANS. Explanation of Carcinogenicity:NONE STATED BY MANUFACTURER. Effects of Overexposure:INHALED-SORE THROAT, COUGHING, HEADACHE, NAUSEA, SHORTNESS OF BREATH, NARCOTIC EFFECT (HIGH CONCENTRATION). INGESTED-GI TRACT IRRITATION, NAUSEA, VOMITING, DIARRHEA. SKIN-REDNESS, PAIN. EYES-PAIN, RED NESS, TERAING, STINGING, SWELLING. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS, IMPAIRED LIVER, KIDNEYS, LYMPHOID SYSTEM, BLOOD, OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHALED-REMOVE TO FRESH AIR. IF BREATHING DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. CALL A PHYSICIAN. INGESTED-IF CONSCIOUS, INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MED ICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. CALL PHYSICIAN IMMEDIATELY. SKIN-REMOVE ANY CONTAMINATED CLOTHES. FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN IMMEDIATELY. EYES-WASH EYES WITH LOTS OF WATER FOR 15 MINUTES, LIFT LIDS. CALL A PHYSICIAN IMMEDIATELY ===================== Fire Fighting Measures ===================== Flash Point:=62.2C, 144.F Autoignition Temp:=237.8C, 460.F Lower Limits:1.1 Upper Limits:12.7 Extinguishing Media:DRY CHEMICAL, ALCOHOL FOAM OR CARBON DIOXIDE. DO NOT USE A SOLID STREAM OF WATER, SINCE THE STREAM WILL SCATTER AND SPREAD THE FIRE. Fire Fighting Procedures:IN THE EVENT OF A FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPEATED IN THE PRESSURE DEMAND OR OTHER POSITIVE MODE. Unusual Fire/Explosion Hazard:WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL, DILUTE SPILLS TO NONFLAMMABE MIXTURES. PROTECT PERSONNEL ATTEMPTING TO STOP LEAK AND DISPERSE VAPORS. ABOVE FLASH POINT, VAPOR-AIR-MIXTURE S ARE EXPLOSIVE WITHIN FLAMMABLE LIMITSNOTED ABOVE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL.REMOVE SOURCES OF IGNITION. WEAR APPROPRIATE PERSONAL PROTECTIVE GEAR. ISOLATE HAZARD AREA. KEEP UNECESSAY PEOPLE FROM ENTERING.CONTAIN & RECOVER IF POSSIBLE. USE NON-S PARKING TOOLS & EQUIPMENT. COLLECT LIQUID IN AN APPROPRIATE CONTAINER OR ABSORB WITH AN INERT MATERIAL & PLACE IN A CHEMICAL WASTE CONTAINER. DO NOT FLUSH TO SEWER. USE WATER SPRAY TO DISPERSE VAPORS Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY, WELL-VENTILATED AREA, AWAY FROM SOURCES OF IGNITION & OXIDIZING MATERIALS. OUTSIDE OR DETACHED STORAGE IS PREFERRED. STORAGE & USE AREA SHOULD BE "NO SMOKING" AREAS. CONTAINERS MA Y BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES. OBSERVE ALL WARNINGS & PRECAUTIONS. Other Precautions:PROTECT AGAINAST PHYSICAL DAMAGE. CONTAINERS SHOULD BE BONDED & GROUNDED FOR TRANSFERS TO AVOID STATIC SPARKS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, A FULL FACEPIECE RESPIRATOR WITH ORGANIC VAPOR CARTIDGE MAY BE WORN UP TO 50 TIMES THE EXPOSURE LIMIT OR THE MAXIMUM USE CONCENTRATION SPECIFIED BY THE APPROPRIATE R EGULATORY AGENCY OR RESPIRATOR SUPPLIER,WHICHEVER IS LOWEST. Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURES BELOW THE AIREBORNE EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS Eye Protection:USE CHEMICAL SAFETY GOGGLES AND/OR FULL FACE SHIELD. Other Protective Equipment:MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA. WEAR IMPERVIOUS CLOTHING, INCLUDING BOOTS, GLOVES, LAB COAT, APRON OR COVERALLS, AS APPROPRIATE, TO PREVENT SKIN CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION SOURCE AND FLASH BACK. CONTACT WITH STRONG OCIDIZERS MAY CAUSE FIRE.SENSITIVE TO STATIC DISCHARGE. FOR EMERGENCIES OR INSTANCES WHERE THE EXPOSRE LEV ELS ARE NOT KNOWN, USE A FULL-FACE POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:=171.1C, 340.F Melt/Freeze Pt:=-70.C, -94.F Vapor Pres:0.8 @ 20 C Spec Gravity:0.90 @ 20 C/4C Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID, MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, STRONG BASES. MAY ATTACK METALLIC ALUMINUM AT HIGH TEMPERATURES. Stability Condition to Avoid:HEAT, FLAMES, IGNITION SOURCES AND INCOMPATIBLES. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY FORM WHEN HEATED TO DECOMPOSITION. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:ORAL RAT LD50: 470 MG/KG. INHALATION RAT LC50: 450 PPM/4HR. SKIN RABBIT LD50: 220 MG/KG; INVESTIGATED AS A TUMORIGEN, MUTAGEN, REPRODUCTIVE EFFECTOR. REPRODUCTIVE TOXICITY: HAS SHOWN TERATOGENIC EFFEC TS IN LABORATORY ANIMALS. ===================== Ecological Information ===================== Ecological:WHEN RELEASED TO THE SOIL, THIS MATERIAL MAY BIODEGRADE TO A MODERATE EXTENT. WHEN RELEASED TO THE SOIL, THIS MATERIAL MAY LEACH INTO GROUNDWATER. WHEN RELEASED TO THE SOIL, THIS MATERIAL IS NOT EXPECTED TO EVAPORATE. WHEN RELEASEDTO WATER, THIS MATERIAL IS EXPECTED TO QUICKLY EVAPORATE. WHEN RELEASED TO WATER, THIS MATERIAL MAY BIODEGRADE TO A MODERATE EXTENT. THE MATERIALHAS AN ESTIMATED BIOCONCENTRATION FACTOR OF LESS THAN 100. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE MANGAED IN AN APPROPRIATE & APPROVED WASTE DISPSOAL FACILITY. PROCESSING, USE OR CONTAMINATION MAY CHANGE THE WASTE MANAGEMENT OPTIONS. STA TE & LOCAL REGULATIONS MAY DIFFER FROM FEDERAL DISPOSAL REGULATIONS. DISPOSE OF CONTAINER IAW FEDERA L, STATE & LOCAL REQUIREMENTS. =================== MSDS Transport Information =================== Transport Information:DOMESTIC, LAND, DOT: TOXIC LIQUID, ORGANIC, N.O.S. (ETHYLENE GLYCOL MONOBUTYL ETHER) HAZARD CLASS 6.1, UN2810, PG III. AIR, ICAO: TOXIC LIQUID, ORGANIC, N.O.S. (ETHYLENE GLYCOL MONOBUTYL ETHER). HAZAR D CLASS: 6.1. UN2810. PACKING GROUPIII. ===================== Regulatory Information ===================== SARA Title III Information:SARA 302: RQ-NO; TPQ-NO. SARA 313: LIST-NO; CHEMICAL CATAGORY-NO. Federal Regulatory Information:RCRA/CERCLA: NO. TSCA: 261.33-NO; 8(D)-YES. State Regulatory Information:NONE SPECIFIED BY MANUFACTURER. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.