FISHER SCIENTIFIC CHEMICAL DIV -- PHENYLARSINE OXIDE SOLUTION -- 6810-00F001629
===================== Product Identification ===================== Product ID:PHENYLARSINE OXIDE SOLUTION MSDS Date:06/22/1993 FSC:6810 NIIN:00F001629 === Responsible Party === Company Name:FISHER SCIENTIFIC CHEMICAL DIV Address:1 REAGENT LN City:FAIR LAWN State:NJ ZIP:07410-2802 Country:US Info Phone Num:201-796-7100/201-796-7523 Emergency Phone Num:201-796-7100/201-796-7523 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:PHENYLARSINE OXIDE CAS:637-03-6 RTECS #:CH8100000 Fraction by Wt: .05-0.2% OSHA PEL:0.5 MG(AS)/CUM Ingred Name:SODIUM HYDROXIDE, CAUSTIC SODA, LYE CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 0.1-0.5% Other REC Limits:2MG/M3 CEILING NIOSH OSHA PEL:2 MG/CUM ACGIH TLV:2 MG/CUM CEILING EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >99.3% Ingred Name:ARSENIC, ARSENICALS (HUMAN & ANIMAL CARCINOGEN BY IARC, IARC GROUP 1; CONFIRMED CARCINOGEN BY NTP & OSHA) *96-2* CAS:7440-38-2 RTECS #:CG0525000 OSHA PEL:0.5 MG/CUM ACGIH TLV:0.2 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INHALATION: CORROSIVE/NEUROTOXIN. 200 MG(NAOH)CUM IMMEDIATELY DANAGEROUS TO LIFE/HEALTH. SKIN: CORROSIVE/SENSITIZER. MAY CAUSE SENSITIZATION DERMATITIS. EYES: MAY CAUSE IRRITATION, CONJUNCTIVITIS/OPTI C NEURITIS. INGESTION: CORROSIVE/NEUROTOXIN. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:INHALATION: CORROSIVE/NEUROTOXIN. 200 MG(NAOH)CUM IMMEDIATELY DANGEROUS TO LIFE/HEALTH. SKIN: CORROSIVE/SENSITIZER. MAY CAUSE SENSITIZATION DERMATITIS. EYES: MAY CAUSE IRRITATION, CONJUNCTIVITIS/OPTIC NEURITIS. INGESTION: CORROSIVE/NEUROTOXIN. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR IMMEDIATELY, IF BREATHING STOPS, GIVE CPR. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. SKIN: WASH W/SOAP/MILD DETERGENT & PLENTY OF WATER FOR 15-20 MINS. EYES: WASH IMMEDIATELY W/PLENTY OF WATER/NORMAL SALINE FOR 15-20 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON COMBUSTIBLE Extinguishing Media:DRY CHEMICAL, CO2, HALON, WATER SPRAY/STANDARD FOAM. LARGE: USE WATER SPRAY, FOG/STANDARD FOAM. Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS/DUSTS; KEEP UPWIND. WEAR SCBA W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT/FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:COVER W/SODA ASH, SCOOP UP & PLACE IN A SUITABLE CONTAINER. ====================== Handling and Storage ====================== Other Precautions:RESPIRATORS OPERATED IN POSITIVE PRESSURE MODE. 20 MG/CUM SUPPLIED AIR-RESPIRATOR W/FULL FACEPIECE, HOOD/HELMET/SUIT, OPERATED IN POSITIVE-PRESSURE MODE. EMPLOYEE MUST WEAR (IMPERVIOUS) CLOTHING & EQU IPMENT TO PREVENT SKIN/EYE CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:100 UG(AS)CUM HALF-MASK AIR-PURIFYING RESPIRATOR W/HIGH EFFICIENCY FILTER. HALF-MASK SUPPLIED-AIR RESPIRATOR. 500 UG(AS)/CUM POWERED AIR-PURIFYING RESPIRATOR W/HIGH-EFFICIENCY FILTER & A FULL FACEPIEC E. SCBA W/A FULL FACEPIECE. (SEE SUPP) Ventilation:LOCAL EXHAUST/MECHANICAL TO MEET EXPOSURE LIMITS. Protective Gloves:REQUIRED Eye Protection:REQUIRED Other Protective Equipment:SPLASH-PROOF/DUST RESISTANT SAFETY GOGGLES & FACESHIELD, EYEWASH FOUNTAIN & QUICK DRENCH SHOWER Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. CONTACT LENSES SHOULD NOT BE WORN. Supplemental Safety and Health RESP PROTECTIION CONT'D: 10MG/(AS)CUM POWERED AIR-PURIFYING RESPIRATOR W/HIGH EFFICIENCY FILTER & FULL FACEPIECE, HALF MASK SUPPLIED-AIR. VAPOR PRESSURE & VAPOR DENSITY INFORMATION IS FOR WATER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Pres:0.7 Vapor Density:14 Spec Gravity:1 Evaporation Rate & Reference:(ETHER=1): >1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS SOLUTION ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:BY THERMAL DECOMPOSITION: ARSINE GAS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.