ASHLAND CHEMICAL COMPANY -- BUTANOL NORMAL -- 6810-00-281-2685
===================== Product Identification ===================== Product ID:BUTANOL NORMAL MSDS Date:05/24/1994 FSC:6810 NIIN:00-281-2685 === Responsible Party === Company Name:ASHLAND CHEMICAL COMPANY Box:2219 City:COLUMBUS State:OH ZIP:43216-2219 Country:US Info Phone Num:614-276-6143 Emergency Phone Num:614-276-6143 CAGE:34897 === Contractor Identification === Company Name:ASHLAND CHEMICAL CO Box:2219 City:COLUMBUS State:OH ZIP:43216-2219 Country:US Phone:614-790-3333/800-274-5263 CAGE:34897 Company Name:CHEMICAL SPECIALISTS AND DEVELOPMENT INC Address:2210 HACKBERRY LN Box:687 City:CONROE State:TX ZIP:77305 Country:US Phone:409-756-1065 CAGE:4N760 ============= Composition/Information on Ingredients ============= Ingred Name:N-BUTYL ALCOHOL (SARA III) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES- LIQUID OR VAPOR CAUSES SEVERE IRRITATION. SKIN- IRRITATION. PROLONGED OR REPEATED EXPOSURE MAY DRY THE SKIN. INHALATION- NOT LIKELY TO CAUSE HARMFUL EFFECTS. CAN CAUSE CNS DEPRESSION. CHRONIC: THIS MATERIAL HAS BEEN SHOWN TO CAUSE HARM TO THE FETUS IN LABORATORY ANIMAL STUDIES. RELEVANCE TO HUMANS IS UNCERTAIN. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYES- STINGING, TEARING, REDNESS, SWELLING AND DAMAGE. SKIN- REDNESS, BURNING, DRYING AND CRACKING. SKIN BURNS AND DAMAGE. INHALATION- IRRITATION. DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE, NAUSEA, H EADACHE, UNCONSCIOUSNESS. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE SKIN, EYE, RESPIRATORY TRACT, LIVER OR KIDNEY MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHIN G. FLUSH WITH WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING UNLESS INSTRUCTED TO DO SO. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:97.0F,36.1C Lower Limits:1.4 Upper Limits:11.2 Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL OR POLYMER FOAM. WATER MAY BE INEFFECTIVE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. USE WATER TO COOL FIRE EXPOSED CONTAINERS AND DILUTE SPILLS. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON SAND OR VERMICULITE & PLACE IN CLOSED CONTAINER FOR DISPOSAL. SHUT OFF ALL SOURCES OF IGNITION. EVACUATE AREA. VENTILATE AREA & WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. WEAR SCBA, RUBBER BOOTS AND HEAVY RUBBER GLOVES. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A FLAMMABLE LIQUID STORAGE ROOM OR CABINET. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:MAKE FREQUENT CAREFUL LEAKAGE INSPECTIONS. ISOLATE FROM OXIDEZERS, CHEMICALS CAPABLE OF SPONTANEOUS HEATING, MATERIALS REACTING WITH AIR OR MOISTURE TO LIBERATE HEAT, IGNITION SOURCES AND EXPLOSIVES. KEEP OUT OF DIRECT SUN & AWAY FROM HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED RESPIRATORS. RESPIRATORS SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION OF CONTAMINANT IN AIR & IN ACCORDANCE WITH OSHA (29 CFR 1910.134). Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED. Protective Gloves:NEOPRENE, NITRILE, PVC OR NATURAL RUBBER Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. CAUTION: FOR MANUFACTURING, PROCESSING, REPACKING OR INDUSTRIAL USE. NOT FOR HOUSHOLD USE. CONTAINE R HAZARDOUS WHEN EMPTY. EMPTIED CONTAINERS RETAIN RESIDUAL LIQUID AND VAPOR. FOLLOW PRECAUTIONS ON LABEL AND IN MSDS. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:=117.C, 242.6F Vapor Pres:4.40 Vapor Density:2.60 Spec Gravity:0.807-0.810 Evaporation Rate & Reference:0.46(N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID. ALCOHOLIC ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE. DISPOSE IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.