SPEX CERTIPREP -- ARSENIC TRIOXIDE, AS28 -- 6810-00N084834
===================== Product Identification ===================== Product ID:ARSENIC TRIOXIDE, AS28 MSDS Date:03/10/1996 FSC:6810 NIIN:00N084834 === Responsible Party === Company Name:SPEX CERTIPREP Address:203 NORCROSS AVE City:METUCHEN State:NJ ZIP:08840 Country:US Info Phone Num:908-549-7144 Emergency Phone Num:800-424-9300 (CHEMTREC) Preparer's Name:SUSHA RAMONE CAGE:04XT3 === Contractor Identification === Company Name:SPEX CERTIPREP INC Address:203 NORCROSS AVE Box:City:METUCHEN State:NJ ZIP:08840 Country:US Phone:732-549-7144 CAGE:04XT3 ============= Composition/Information on Ingredients ============= Ingred Name:ARSENIC TRIOXIDE; (AS*2O*3) (SARA 302/313) (CERCLA) CAS:1327-53-3 RTECS #:CG3325000 Fraction by Wt: 100% OSHA PEL:SEE 1910.1018 ACGIH TLV:0.01 MG/M3, A1 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 20 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: ARSENIC TRIOXIDE AS POWDER CAUSES RESP CANCER. IT IS BELIEVED, HOWEVER, THAT A PROMOTER SUCH AS SO*2, METAL OXIDE FUMES, SMOKING CIGARETTES, IRRITANT ACID GASES &/OR ASSOC METALS, CU, FE, & PB MAY BE REQUIRED TO ELICIT CARCIN RESPONSE. AS*2O*3 PURE & CRUDE IN AQUEOUS SOLN WAS FOUND TO BE ALMOST (EFTS OF OVEREXP) Explanation of Carcinogenicity:ARSENIC TRIOXIDE: IARC MONO, SUPP, VOL 7, PG 100, 1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN (SUP DAT) Effects of Overexposure:HLTH HAZ: TENFOLD MORE TOX THAN AS*2O*3 ADMINISTERED DRY BY SAME ROUTE. IF INHALED, INGESTED/ABSORBED THRU SKIN, ARSENIC & ITS CMPDS CAN BE POISONOUS & MAY CAUSE DEATH. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCASIONALLY LIFTING UPPER & LOWER EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING, THEN FLUSH W/WATER FOR AT LEAST 15 MINUTES. WASH CLOTHING THORO BEFORE REUSE . INHAL: MOVE TO FRESH AIR. INGEST: DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL HELP. IF CONSCIOUS, GIVE A LARGE QUANTITY OF WATER OR MILK. IF IRRIT CONTINUES, GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MAY GIVE OFF TOXIC FUMES IN FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE THE AREA OF THE SPILL. VENTILATE AREA IMMEDIATELY. CONTAIN MATERIAL IN A BAG AND HOLD FOR PROPER DISPOSAL. WASH SPILL SITE ONCE ALL MATERIAL IS PICKED UP. WEAR PROTECTIVE CLOTHING, BOOTS AND GLOVES IN ADDITION TO NIOSH APPROVED SCBA. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A TIGHTLY SEALED CONTAINER. Other Precautions:HIGH TEMPERATURE HAZARD. CARCINOGEN AND HIGHLY TOXIC. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR. Ventilation:CHEMICAL FUME HOOD. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . LAB COAT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SOL IN WATER: COLD-3.7G/100ML; HOT-10.14G/100ML. EXPLAN OF CARCIN: TO BE CARCIN. OSHA REGULATED: CFR 29 1910.1018. HUMAN: LUNG TUMORS. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:594F,312C Spec Gravity:3.738 Solubility in Water:SUP DAT Appearance and Odor:WHITE POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, OXIDIZING AGENTS, AND HALOGENS. Stability Condition to Avoid:HEAT. Hazardous Decomposition Products:TOXIC FUMES OF ARSENIC OXIDES. MAY DECOMPOSE UPON EXPOSURE TO WATER OR MOIST AIR. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL AGENCY FOR REGULATIONS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.