MATHESON GAS PRODUCTS -- VINYL CHLORIDE -- 6810-00N034925
===================== Product Identification ===================== Product ID:VINYL CHLORIDE MSDS Date:10/01/1985 FSC:6810 NIIN:00N034925 === Responsible Party === Company Name:MATHESON GAS PRODUCTS Address:932 PATTERSON PLANK RD City:EAST RUTHERFORD State:NJ ZIP:07073 Country:US Info Phone Num:201-933-2400 Emergency Phone Num:201-933-2400 CAGE:0FB11 === Contractor Identification === Company Name:MATHESON GAS PRODUCTS Address:30 SEAFIEW DRIVE Box:City:SEACAUCUS State:NJ ZIP:07096 Country:US Phone:201-867-4100, CHEMTREC 800-424-9300 CAGE:0FB11 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENEM, CHLORO-; (VINYL CHLORIDE) (SARA III) CAS:75-01-4 RTECS #:KU9625000 OSHA PEL:SEE 1910.1017 ACGIH TLV:5 PPM, A1; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:INHAL MAY CAUSE DROWS, BLURRED VISION, STAG GAIT, & TINGLING & NUMBNESS IN THE FEET & HANDS. IN HIGH CONC VINYL CHLORIDE ACTS AS AN ANESTHETIC. CONTACT WITH LIQ VINYL CHLORIDE MAY CAUSE SEVERE I RRITATION & BURNS. CHRONIC: VINYL CHLORIDE IS A RECOGNIZED CARCINOGEN & HAS CAUSED CANCER IN MAN.(EFTS OF OVEREXP) Explanation of Carcinogenicity:VINYL CHLORIDE: KNOWN CARCINOGEN (NTP), GROUP 1 (IARC); OSHA REGULATED Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: MOVE VICTIM TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. EYE/SKIN: IMMED FLUSH EYE/SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MIN. REMOVE CON TAMINATED CLOTHING AND SHOES. CALL A PHYSICIAN. INGEST: GET MD IMMEDIATELY . NOTE: SKIN BURNS CAN BE TREATED BY THE APPLICATION OF MAGNESIUM PASTE (MAGNESIUM OXIDE AND GLYCERINE). ===================== Fire Fighting Measures ===================== Lower Limits:4% Upper Limits:22% Extinguishing Media:TO EXTING A VINYL CHLORIDE FIRE STOP THE FLOW OF GAS. IF THE FLOW CANNOT BE STOPPED, LET THE FIRE BURN ITSELF(SUPP DATA) Fire Fighting Procedures:FIRE FIGHTERS MUST WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . FIREIGHTERS TURNOUT GEAR IS INADEQUATE. Unusual Fire/Explosion Hazard:CYLINDERS THAT ARE EXPOSED TO FIRE MAY RUPTURE WITH VIOLENT FORCE. EXTING SURROUNDING FIRE & KEEP CYLINDERS COOL USING A WATER SPRAY APPLIED FROM THE(SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. PERSONNEL EQUIPPED W/SPECIAL PERSONAL PROTECTIVE SUITS FOR FIRE/CHEMICALS AND POSITIVE PRESSURE NIOSH/MSHA APPROVED SCBA CAN RE-ENTER THE AREA AND ATTEMPT TO STOP LEAK. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:CYLINDERS SHOULD BE STORED AND USED IN DRY, WELL VENT AREAS AWAY FROM SOURCES OF HEAT OR IGNITION. DO NOT STORE WITH OXIDIZERS. Other Precautions:BEFORE USING: 1)SECURE CYLINDER TO PVNT IT FROM FALLING OR BEING KNOCKED OVER. 2) INSTALL CHECK VALVES/TRAPS TO PVNT SUCKBACK TO CYLNDER. 3)LEAK CHECK LINES & EQUIP. 4) HAVE APPRVD RESP PROT & OTHER P ROT EQUIP. 5) HAVE AN EMER (SUPP DAT ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED POSITIVE PRESSURE SCBA SHOULD BE WORN IF IT IS SUSPECTED THAT VINYL CHLORIDE IS IN THE AIR. Ventilation:NONE SPECIFIED BY MANUFACTURER. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:CHEM WORK GOGG/FULL LENGTH FSHLD . Other Protective Equipment:EYE WASH STATIONS & SAFETY SHOWERS READILY AVAILABE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXTING MEDIA:OUT WHILE COOLING CYLINDER & SURROUNDINGS USING A H*2O SPRAY. EXPLO HAZ:MAX POSS DISTANCE. FLAMM & TOX GASES MAY SPREAD FROM A SPILL AFTER FIRE IS EXTING & BE SUBJECT TO REIGNIT. THERMAL DECOMP PRODS MAY INCL HCL & PHOSGENE . OTHER PREC: PLAN COVERING STEPS TO BE TAKEN IN CASE OF ACCIDENTAL RELEASE. ================== Physical/Chemical Properties ================== HCC:G2 Boiling Pt:B.P. Text:7.2F,-13.8C Melt/Freeze Pt:M.P/F.P Text:-245F,-154C Vapor Pres:234KPA@21C Spec Gravity:2.21 Solubility in Water:1.07 CM3/1 ML H*2O Appearance and Odor:COLORLESS, HIGHLY FLAMM GAS WITH A PLEASANT, SWEET ODOR AT HIGH CONC. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATLS, ACTIVE METALS, ALUMINUM ALLOYS AND ORGANOMETALLICS. Stability Condition to Avoid:AVOID EXPOSURE TO SUNLIGHT, HEAT, AIR, OXYGEN PEROXIDES AND OTHER STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CARBON MONOXIDE. Conditions to Avoid Polymerization:OXYGEN (AIR), HEAT, SUNLIGHT, MOISTURE AND FREE RADICAL INITIATORS OR OTHER CATALYTIC MATERIALS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.