OCCIDENTAL CHEMICAL CORP DIV OCCIDENTAL PETROLEUM -- SODIUM CHROMATE ANHYDROUS -- 6810-00-264-6714
===================== Product Identification ===================== Product ID:SODIUM CHROMATE ANHYDROUS MSDS Date:12/30/1993 FSC:6810 NIIN:00-264-6714 === Responsible Party === Company Name:OCCIDENTAL CHEMICAL CORP DIV OCCIDENTAL PETROLEUM Address:345 3RD ST (ELECTROCHEMICALS DIV) Box:728 City:NIAGARA FALLS State:NY ZIP:14302 Country:US Info Phone Num:716-278-7000 Emergency Phone Num:716-278-7000 CAGE:91784 === Contractor Identification === Company Name:OCCIDENTAL CHEMICAL CORP (OXYCHEM)SHORT ABBREVIAT Address:360 RAINBOW BLDVD SOUTH Box:728 City:NIAGARA FALLS State:NY ZIP:14302 Country:US Phone:1-800-733-3665 CAGE:91784 Company Name:OCCIDENTAL CHEMICAL CORPORATION Address:5005 LYNDON B JOHNSON FWY Box:City:DALLAS State:TX ZIP:75244-6198 Country:US Phone:800-752-5151/972-404-3800 CAGE:0AH54 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CHROMATE (SARA III) CAS:7775-11-3 RTECS #:GB2955000 Fraction by Wt: 100% OSHA PEL:0.1 PPM CRO3;CEILING ACGIH TLV:0.05 MG CR/M3; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 52 MG/M3 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION-MAY CAUSE IRRITATION OF THE NASAL SEPTUM AND RESPIRATORY TRACT. SKIN-MAY RARELY CAUSE ALLERGIC CONTACT DERMATITIS. EYE-WILL CAUSE SEVERE IRRITATIO AND POTENTILA DAMAGE TO THE EYES. INGESTIO N-CAN CAUSE SEVERE TISSUE DESTRUCTION. KEDNEY FAILURE MAY FOLLOW & RESULT IN DEATH. Explanation of Carcinogenicity:THERE IS SUFFICIENT EVIDENCE TO ESTABLISH A CAUSAL RELATIONSHIP BETWEEN THE AGENT AND HUMAN CANCER. Effects of Overexposure:MAY CAUSE BLINDNESS. MAY CAUSE DEEP PENETRATING ULCERS ON SKIN. PROLONGED OR REPEATED SKIN CONTACT ON BROKEN SKIN MAY CAUSE CHROME SORES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES-IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN. SEEK PHYSICIAN. SKIN-IMMEDIATELY WASH AREA WITH PLENTY OF WATER & SOAP FOR AT LEAST 15 MIN. SEEK PHYSICIAN. INHALATION-REMO VE TO FRESH AIR. IF BREATHING IS HARD, HAVE TRAINED PERSON ADMINSTER OXYGE, IF BREATHING HAS STOPPED, GIVE CPR. SEEK PHYSICIAN. INGESTION-DO NOT INDUCE VOMITING. GIVE LARGE AMOUNTS OF WATER. ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Extinguishing Media:WATER FOG, DRY CHEMICAL OR CARBON DIOXIDE MAY BE USED IN AREAS WHERE PRODUCT IS STORED. Fire Fighting Procedures:NIOSH/MSHA PRESSURE DEMAND, SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN BY FIRE FIGHTERS IN AREAS WHERE THIS PRODUCT IS STORED. Unusual Fire/Explosion Hazard:OXIDIZER. AVOID CONTACT WITH ORGANIC MATERIAL ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK. DIKE. REMOVE WITH VACUUM TRUCK. TREAT SPILL AREA WITH REDUCING AGENT AND NEUTRALIZE WITH WEAK BASE. SOAK UP WITH INERT ABSORBENT MATERIAL, PLACE IN A CLOSED, LABELLED CONTAINER & STORE IN A SAFE PLACE TO AWAIT DISPOSAL. Neutralizing Agent:SODIUM BICARBONATE, SODA ASH, LIME. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN CLOSE PROXIMITY TO COMBUSTIBLE MATERIALS. STORE IN TIGHTLY CLOSED CONTAINERS AWAY FROM SOURCES OF HEAT. Other Precautions:POISONOUS SOLIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPVD RESPIRATOR WHERE DUST,MIST OR FUMES MAY BE GENERATED. Ventilation:LOCAL EXHAUST TO ELIMINATE MISTS/FUMES/GASES. Protective Gloves:RUBBER/PLASTIC Eye Protection:GOGGLES/FACE SHIELD Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE WASH STATION Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING (TAKE SHOWER AFTER WORK;USE FRESH CLOTH DAILY). LAUNDER CONTAMINATED CLOTHING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:T4 Melt/Freeze Pt:M.P/F.P Text:1458F,792C Spec Gravity:2.7 pH:8.4-9 Solubility in Water:44%@68F(20C) Appearance and Odor:BRIGHT YELLOW CRYSTALS, NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH ORGANIC MATERIALS, OILS, GREASES AND ANY OXIDIZABLE MATERIALS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE Conditions to Avoid Polymerization:MATERIAL IS NOT KNOWN TO POLYMERIZE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE & FEDERAL REGULATIONS.NEVER FLUSH TO SEWER. SIGNIFICANT SPILLS SHOULD BE REPORTED TO APPROPRIATE AGENCIES Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.