ICI AMERICAS INC.,ICI PHARMACEUTICALS DIV -- TRIETHANOLAMINE 99 -- 6810-00-281-2192
===================== Product Identification ===================== Product ID:TRIETHANOLAMINE 99 MSDS Date:01/21/1986 FSC:6810 NIIN:00-281-2192 === Responsible Party === Company Name:ICI AMERICAS INC.,ICI PHARMACEUTICALS DIV Address:CONCORD PIKE AND MURPHY ROAD City:WILMINGTON State:DE ZIP:19897 Country:US Info Phone Num:302-886-3000 Emergency Phone Num:800-327-8633 MEDICAL CAGE:0A273 === Contractor Identification === Company Name:AMJAY CORP. DBA AMJAY CHEMICALS Address:11200 WESTHEIMER SUITE 310 Box:218786 City:HOUSTON State:TX ZIP:77218-8786 Country:US Phone:713-492-2000 CAGE:64184 Company Name:ZENECA INC., ZENECA PHARMACEUTICALS GROUP Address:1800 CONCORD PIKE Box:City:WILMINGTON State:DE ZIP:19803-2902 Country:US Phone:302-886-3000 CAGE:0A273 ============= Composition/Information on Ingredients ============= Ingred Name:TRIETHANOLAMINE CAS:102-71-6 RTECS #:KL9275000 Fraction by Wt: 99% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 8,700 MG/KG Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES:MODERATE IRRITANT. MAY CAUSE BURNS. SKIN:SLIGHT IRRITANT. INHALED:DUE TO LOW VAPOR PRESSURE, AN UNLIKELY EXOPOSURE. VAPORS OR MISTS MAY CAUSE NASAL AND RESPIRATORY IRRITATION. INGESTED:SINGLE DO SE IS PRACTICALLY NON-TOXIC. WILL CAUSEG/I IRRITATION. Explanation of Carcinogenicity:THIS PRODUCT IS NOT LISTED BY NTP, IARC, OR OSHA Effects of Overexposure:EYES:REDNESS,TEARING. INHALED:UNLIKELY EXPOSURE. VAPORS/MISTS CAUSE RESPIRATORY IRRITATION. INGESTED:G/I IRRITATION, NAUSEA, VOMITING, DIARRHEA. REPEATED INGESTION MAY CAUSE REVERSABLE LIVER/KIDNEY EF FECTS. Medical Cond Aggravated by Exposure:SUGGESTS POSSIBLE DERMATITIS WITH PROLONGED/REPEATED SKIN CONTACT. ======================= First Aid Measures ======================= First Aid:IF SYMPTOMS PERSIST OR ARE SEVERE, SEE A DOCTOR. EYE:FLUSH W/WATER 15 MIN. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. INHALED:REMOVE TO FRESH AIR. AID/RESTORE BREATHING IF NECESSARY. INGESTED:DO NOT INDUCE VOMITING. GIVE 2 LARGE GLASSES OF MILK OR WATER TO DILUTE & GET IMMEDIATE MEDICAL CARE. NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:410F,210C Lower Limits:NO DATA Upper Limits:NO DATA Extinguishing Media:WATER FOG,ALCOHOL FOAM,CARBON DIOXIDE,DRY CHEMICAL, HALON 1211. WATER OR FOAM MAY CAUSE FROTHING. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING FIRE. USE WATER SPRAY TO COOL NEARBY FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:"NONE KNOWN" ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PERSONAL PROTECTION DURING CLEAN UP. SOAK UP WITH ABSORBENT AND SHOVEL INTO DISPOSAL CONTAINER. WASH SPILL AREA WITH WATER AND FLUSH TO SEWER SERVICED BY WASTE WATER TREATMENT FACILITY. Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY MFR. ====================== Handling and Storage ====================== Handling and Storage Precautions:PREVENT SKIN AND EYE CONTACT. AVOID BREATHING VAPORS OR AEROSOLS. DO NOT STORE IN ALUMINUM CONTAINERS. Other Precautions:'EMPTY' CONTAINERS MAY CONTAIN RESIDUE OR VAPOR. TREAT THEM WITH THE RESPECT DUE FULL ONES. DISPOSE OF USED CONTAINERS BY TRIPPLE RINSING AND RECYCLE OR RECONDITION, OTHERWISE DESTROY BY PUNCTURING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR EQUIPPED WITH HIGH EFFICIENCY FILTER COMBINED WITH CARTRIDGE APPROVED FOR AMMONIA AND METHYLAMINE. Ventilation:USE LOCAL EXHAUST TO KEEP EXPOSURES TO A MINIMUM. Protective Gloves:IMPERVIOUS Eye Protection:CHEMICAL SPLASH GOGGLES PLUS FACE SHIELD Other Protective Equipment:APRON, ARM COVERS OR FULL BODY SUIT AS REQUIRED BY CONDITIONS. Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:639F,337C Vapor Pres:<0.01 Vapor Density:5.14 Spec Gravity:1.12 pH:ALKA. Solubility in Water:SOLUBLE Appearance and Odor:PALE YELLOW VISCOUS LIQUID WITH SLIGHT AMMONICAL ODOR Percent Volatiles by Volume:98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS,STRONG MINERAL ACIDS. ATTACKS ALUMINUM, COPPER & ITS ALLOYS AND GALVANIZED IRON. Stability Condition to Avoid:OPEN CONTAINERS; WILL ABSORB MOISTURE AND CARBON DIOXIDE. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,NITROGEN OXIDES,AMMONIA. REACTION WITH ALUMINUM WILL RELEASE FLAMMABLE HYDROGEN GAS. Conditions to Avoid Polymerization:WILL NOT OCCUR ==================== Disposal Considerations ==================== Waste Disposal Methods:MFR:"DISCARDED PRODUCT IS NOT A HAZARDOUS WASTE UNDER RCRA 40CFR261." HMIS:CHECK WITH REGULATIONS AND DISPOSE I/A/W FEDERAL, STATE & LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.