BOLIDEN INTERTRADE INC -- COPPER SULFATE -- 6810-00-236-5680
===================== Product Identification ===================== Product ID:COPPER SULFATE MSDS Date:12/27/1991 FSC:6810 NIIN:00-236-5680 === Responsible Party === Company Name:BOLIDEN INTERTRADE INC Address:3400 PEACHTREE RD NE SUITE 401 City:ATLANTA State:GA ZIP:30326 Country:US Info Phone Num:404-239-6700/404-233-6811 Emergency Phone Num:800-424-9300 CAGE:0V5C3 === Contractor Identification === Company Name:BOLIDEN INTERTRADE INC Address:3400 PEACHTREE RD NE SUITE 401 Box:City:ATLANTA State:GA ZIP:30326 Country:US Phone:404-239-6700/404-233-6811 CAGE:0V5C3 ============= Composition/Information on Ingredients ============= Ingred Name:CUPRIC SULFATE (SARA III) CAS:7758-98-7 RTECS #:GL8800000 Fraction by Wt: 99% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG (CU)/M3 ACGIH TLV:1 MG(CU)/M3; 9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 300 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION MAY CAUSE IRRITATION OF MUCOUS MEMBRANES. CONTACT MAY CAUSE SKIN IRRITATION AND INJURE EYES. INGESTION MAY CAUSE HEMOLYSIS, URINARY SYSTEM EFFECTS, JAUNDICE, PROSTRATION, ANURIA, ANE MIA, COMA. CHRONIC: PROLONGED OR REPEATED EXPOSURE MAY CAUSE SYSTEMIC EFFECTS (DAMAGE TO KIDNEY AND LIVER FUNCTION). Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALED: COUGHING, SNEEZING, WHEEZING, SHORTNESS OF BREATH. EYES: BURNING, PAIN, REDNESS, DISCOMFORT. SKIN: REDNESS, ITCHING, DISCOMFORT. INGESTED: VOMITING, GASTROENTERIC PAIN, HEMORRHAGES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALED: REMOVE TO FRESH AIR AND SEEK MEDICAL AID. EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL AID. SKIN: REMOVE CONTAMINATED CLOTHES. WASH WITH SOAP AND WATER. INGESTED: IF C ONSCIOUS, GIVE 1-2 GLASSES OF WATER, THEN INDUCE VOMITING. IMMEDIATELY CALL DOCTOR OR POISON CONTROL CENTER. NOTE TO DR- PROBABLE MUCOSAL DAMAGE MAY PRECLUDE GASTRIC LAVAGE. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. KEEP WATER FROM FIRE FIGHTING FROM ENTERING WATERWAYS AND SEWERS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. SWEEP UP, PLACE IN A BAG AND HOLD FOR DISPOSAL. AVOID RAISING DUST. WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA. KEEP TIGHTLY CLOSED. Other Precautions:NONE FOUND. NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR EMERGENCY OCCURS; USE NIOSH/MSHA APPROVED RESPIRATOR. USE IN ACCORDANCE WITH 29 CFR 1910.134. Ventilation:USE ADEQUATE MECHANICAL VENTILATION TO MAINTAIN EXPOSURE BELOW PEL/TLV. Protective Gloves:RUBBER Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES Other Protective Equipment:CLOTHING TO PREVENT SKIN CONTACT. EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH AHNDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V7 Boiling Pt:B.P. Text:302F,150C Melt/Freeze Pt:M.P/F.P Text:230F,110C Vapor Pres:7.3 MM HG Spec Gravity:2.284 Solubility in Water:APPRECIABLE Appearance and Odor:BLUE CRYSTALS OR POWDER; NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROXYLAMINE, MAGNESIUM, FINELY DIVIDED METALS. Stability Condition to Avoid:CONTACT WITH INCOMPATIBLE MATERIALS. AVOID HIGH TEMPERATURES, EXPOSURE TO AIR. Hazardous Decomposition Products:OXIDES OF SULFUR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE IN WATER; PRECIPITATE AS ITS SULFIDE, ADJUSTING PH TO 7; FILTER INSOLUBLES AND DISPOSE OF THEM IN A HAZWASTE SITE. DESTROY ANY EXCESS SULFIDE WITH SODIUM HYPOCHLORITE, NEUTRALIZE SOLUTION BE FORE FLUSHING DOWN DRAIN (SIGMA-ALDRICH). Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.