NATIONAL INSTITUTE OF STANDARDS AND TECH -- MERCURY SPECTROMETRIC STANDARD SOLUTION, 3133 -- 6640-00N056830
===================== Product Identification ===================== Product ID:MERCURY SPECTROMETRIC STANDARD SOLUTION, 3133 MSDS Date:04/01/1989 FSC:6640 NIIN:00N056830 === Responsible Party === Company Name:NATIONAL INSTITUTE OF STANDARDS AND TECH Address:E BLDG 128 RT 2 QUINCY ORCHARD RD City:GAITHERSBURG State:MD ZIP:20899 Country:US Info Phone Num:301-975-2019 Emergency Phone Num:301-975-2000 CAGE:9Y292 === Contractor Identification === Company Name:NATIONAL INSTITUTE OF STANDARDS & TECH Address:RT 270 & QUINCY ORCHARD E BLDG 128 Box:City:GAITHERSBURG State:MD ZIP:20899 Country:US Phone:301-975-6439 CAGE:9Y292 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID (SARA 302/313) (CERCLA) SPEC GRAV:20/4C:1.36, MP:-4F(-20C), %VOLAT:100 @ 122C, SOL IN H*2O:COMPLETE. CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 10% OSHA PEL:2 PPM ACGIH TLV:2 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MERCURY (II) NITRATE (1:2); (MERCURIC NITRATE) (SARA 313) LD50(ORAL,RAT):51.4 MG/KG. VAP DENS:4.3, MP:174F,79C, (ING 3) CAS:10045-94-0 RTECS #:OW8225000 Fraction by Wt: 1.62% OSHA PEL:0.1 MG (HG)/M3 ACGIH TLV:0.025 MG(HG)/M3 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ING 2:BP:DECOMPOSES, SOL IN H*2O:SOLUBLE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 2 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE/CHRONIC:THIS MATERIAL IS CORROSIVE TO ALL BODY TISSUES. (HNO*3) CHRONIC:SYMPTOMS INVOLVE THE CNS WITH TREMORS AND VARIOUS NEUROPSYCHIATRIC DISTURBANCES. (H*G(NO*3)*2) SYMPS OF EXPOS:IRRITATION, DIFFICULTY BREATHING, BURNING SENSATION, YELLOW SKIN DISCOLORATION. (HNO*3) PNEUMONITIS, CHEST PAINS, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HEALTH HAZARDS:DYSPNEA, COUGHING. IN THE LATTER STAGES STOMATITIS, GINGIVITIS AND SALIVATION OCCUR. (H*G(NO*3)*2). MERCURY COMPOUNDS APPEAR ON NAVY LISTING OF OCCUP CHEM HAZS. SEEK CONSULTATION FROM A PPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLNG & EXPOS INFO . Medical Cond Aggravated by Exposure:IRRITATION OF EYES, SKIN, LUNGS, CAN CAUSE PERMANENT BLINDNESS OR MAY BE FATAL. (HNO*3) DERMATITIS, STOMATITIS, GINGIVITIS, KIDNEY DAMAGE. (H*G(NO*3)*2). ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH WITH WATER FOR AT LST 15 MIN, INCLUDING UNDER EYELIDS. REMOVE ANY CLOTHING THAT IS CONTAM. CONT MD. SKIN:WASH IMMED WITH SOAP & WATER. REMOVE CONTAM CLTHG UNDER SAFETY SHOWER. GET MED ATTN. INHAL:REMOVE TO FRESH IAR. ADMINO*2 IF NEC & GET MED ATTN. INGEST:IF CONSCIOUS , GIVE 2-3 GLASSES WATER, THEN MILK OF MAGNESIA/LIMEWATER. CONTACT MD. DO NOT INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point:NON FLAMMABLE Extinguishing Media:USE WATER ON FIRES INVOLVING NITRIC ACID TO DILUTE THE ACID AND TO ABSORB THE LIBERATED OXIDES OF NITROGEN. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DANGEROUS FIRE RISK IN CONTACT WITH ORGANIC MATERIALS. NONFLAM, HOWEVER, A STRONG OXIDIZING AGENT WHICH CAN REACT W/COMBUST MATLS TO CAUSE FIRES. ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE ADEQUATE VENTILATION. REMOVE SOURCES OF IGNITION. SURFACES CONTAMINATED BY SPILLS SHOULD BE COVERED WITH SODIUM BICARBONATE OR SODA ASH TO NEUTRALIZE THE ACID. WASH THE NEUTRALIZED SLURRY DOWN THE DRAIN WITH EXCESS WATER. Neutralizing Agent:SODIUM BICARBONATE, SODA ASH. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE CNTNRS IN CLEAN, COOL, WELL-VENT AREA AWAY FROM ORGANIC CHEMS, STRONG BASES, METAL POWDERS, CARBIDES, SULFIDES & ANY READILY OXIDIZABLE MATL. Other Precautions:PROTECT FROM DIRECT SUNLIGHT. PREPLACEMENT & ANNUAL MED EXAMINATIONS W/EMPHASIS ON RESP TRACT, SKIN IRRITS, DENTAL EROSION, & LUNG FUNCTION TESTS SHOULD BE PROVIDED TO WORKERS FREQUENTLY EXPOS TO NITR IC ACID. WHEN GASEOUS NO*X FORMS(SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:THE NITROGEN OXIDES PRODUCED FROM THE ACID ARE ALL TOXIC, AND PROPER VENTILATION SHOULD ALWAYS BE USED. Protective Gloves:NEOPRENE GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:BODY SHIELDS SHOULD BE USED WHERE SPLASHING MAY OCCUR. CHEM SFTY SHOWERS & EYEWASH STATIONS MUST BE READILY (SUP DAT) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health APPEAR/ODOR:ODOR. MERCURIC NITRATE:WHITE OR YELLOWISH CRYSTALS OR POWDER. HAZ DECOMP PRODS:(HNO*3) THERMAL DECOMP YIELDS MERCURY OXIDE & OXIDES OF NITROGEN. (H*G(NO*3)*2) OTHER PREC:FROM A SPILL, EVAC UATE AREA. SPECIALLY TRAINED WORKERS MUST HANDLE THE SPILL. OTHER PROT EQUIP:AVAIL IN AREAS OF STOR & HNDLG. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SEE INGS Melt/Freeze Pt:M.P/F.P Text:SEE INGS Vapor Density:SEE INGS Spec Gravity:SEE INGS Solubility in Water:SEE INGREDIENTS Appearance and Odor:NITRIC ACID:WATER WHITE TO SLIGHTLY YELLOW LIQ W/CHARACTERISTIC NO*2 (SUPP DATA Percent Volatiles by Volume:SEEING ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT WITH ORGANIC MATERIALS (WOOD, PAPER, ALCOHOL, TURPENTINE, H*2S). (HNO*3) Stability Condition to Avoid:HEAT Hazardous Decomposition Products:NITROUS OXIDES, INCLUDING NO, NO*2, N*2O*3 & N*2O CAN BE PRDCD UPON DECOMP/REACTION OF HNO*3. ALL ARE TOX. (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:FEDERAL, STATE AND LOCAL REGULATIONS MUST ALWAYS BE CONSIDERED PRIOR TO SEWER DISPOSAL. NEUTRALIZED SPILL MAY BE PICKED UP BY USE OF ABSORBENTS AND DISPOSED OF AS SOLID WASTE IN A LANDFILL. USE CLEAN SAND OR VERMICULITE AS ABSORBENT SOLID. 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