BARIUM AND CHEMICALS INC -- BARIUM CHROMATE -- 6850-00N012831
===================== Product Identification ===================== Product ID:BARIUM CHROMATE MSDS Date:10/13/1997 FSC:6850 NIIN:00N012831 Status Code:A === Responsible Party === Company Name:BARIUM AND CHEMICALS INC Address:COUNTY RD 44 City:STEUBENVILLE State:OH ZIP:43952 Country:US Info Phone Num:614-282-9776 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:20865 === Contractor Identification === Company Name:BARIUM AND CHEMICALS INC Address:COUNTY RD 44 Box:218 City:STEUBENVILLE State:OH ZIP:43952 Country:US Phone:740-282-9776 CAGE:20865 ============= Composition/Information on Ingredients ============= Ingred Name:BARIUM CHROMATE; (BARIUM COMPOUNDS) CAS:10294-40-3 RTECS #:CQ8760000 OSHA PEL:0.5 MG/M3 (CR) ACGIH TLV:0.5 MG/M3 (CR) Ingred Name:BARIUM (SARA 313) CAS:7440-39-3 RTECS #:CQ8370000 Fraction by Wt: 54.2% OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 (BA) (MFR) Ingred Name:CHROMIUM (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 39.5% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHAL:SYMPS OF EXPOS:VOMIT, VIOLENT DIARR, ABDOM PAIN, DFCLTY IN BRTHG, SLOW PULSE & IRREG HEARTBEAT. MAY CAUSE BLEEDING & ULCERATION OF NASAL SEPTUM, SORE THROAT, COUGH & POSS LIVER DMG. IN LG DOSES WILL CAUSE CARD & RESP FAILURE & HEMORRS IN GI TRACT & KIDNEYS. SKIN/EYE CONT:IRRIT. CAL PROP 65:BARIUM(EFTS OF OVEREXP) Explanation of Carcinogenicity:BARIUM CHROMATE:IARC MONOGRAPHS, VOL 49, PG 49, 1990:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE CARCIN. Effects of Overexposure:HLTH HAZ:CHROMATE CONTAINS HEXAVALENT CHROMIUM. HEXAVALENT CHROMIUM IS ON CALIFORNIA GOVERNOR'S LIST, "CHEMS KNOWN TO CAUSE CANCER/REPRO TOX". USE CARE WHEN HNDLG THIS CHEM. TOX:WORKERS MAY EXPER INCR INCIDENCE OF LUNG CANCER. POISONING MAY AFFECT BLOOD, CNS, LIVER & KIDNEYS. MATL IS CARCINOGENIC. Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING SKIN PROBLEMS. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE VICTIM TO FRESH AIR, IF VICTIM HAS DFCLTY BRTHG GIVE OXYG. IF VICTIM HAS STOPPED BRTHG GIVE ARTF RESP & CALL FOR PROMPT MED ATTN. SKIN:REMOVE CONTAM CLTHG & WASH CONT POINTS THORO W/SOAP & WATER. WASH CONTAM CLTHG BEFORE REUSE. EYES:HOLD LIDS OPEN & FLUSH W/CLEAN WATER FOR AT LST 15 MINS. GET PROMPT MED ATTN. INGEST:CALL FOR PROMPT MED ATTN. REMOVE CHROMATES FROM STOM BY GASTRIC LAVAGE. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE OR WATER SPRAY. LARGER FIRES; USE FOG. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . IN STOR AREA USE UNMANNED HOSE HOLDER & W/DRAW FROM AREA UNTIL FIRE IS OUT. RUNOFF IS TOX; AVOID CONT & (SUPDAT) Unusual Fire/Explosion Hazard:NON-FLAMMABLE. REDUCING AGENTS MAY REACT VIOLENTLY. RUNOFF AND WASTE ARE TOXIC, PREVENT FROM ENTERING NATURAL WATERWAYS. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP COMBUSTIBLES AWAY FROM SPILLED MATL. SHOVEL UP SPILLED MATL INTO CLEAN DRY CONTAINERS & COVER. REMOVE CONTAINERS FROM SPILL AREA. RUNOFF & WASTE ARE TOXIC, PREVENT FROM ENTERING NATURAL WATERWAYS . Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT W/REDUCING AGENTS. PREVENT CONTACT W/SKIN. PREVENT RUNOFF FROM SPILL OR FIRE FROM REACHING NATURAL WATERWAYS. Other Precautions:NON-FLAMMABLE. REDUCING AGENTS MAY REACT VIOLENTLY. KEEP AWAY FROM FOODS. USE CARE WHEN HANDLING THIS CHEMICAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED HIGH EFFICIENCY PARTICULATE RESPIRATOR FULL FACE MASK. WHERE EXPOSURE LIMIT MAY BE EXCEEDED USE NIOSH APPROVED DUST RESPIRATOR. Ventilation:USE ADEQUATE VENTILATION TO MEET EXPOSURE LIMITS. Protective Gloves:RUBBER GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT) Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER . USE FULL COVERAGE IMPERVIOUS CLOTHING TO PREVENT ANY (SUPDAT) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EYE PROT:& FULL LENGTH FACESHIELD . OTHER PROT EQUIP:POSSIBLE CONTACT W/MATERIAL. ================== Physical/Chemical Properties ================== Spec Gravity:4.5 Solubility in Water:NOT SOLUBLE Appearance and Odor:YELLOW POWDER; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/REDUCING AGENTS. Stability Condition to Avoid:MAY REACT VIGOROUSLY W/REDUCING AGENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . CONTAMINATED SWEEPINGS & RESIDUE ARE CONSIDERED A TOXIC WASTE. THIS RESIDUE MUST BE DISPOSED OF AT A LICENSED TOXIC WASTE DUMP. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.