MATHESON TRI-GAS, INC. -- HYDRIODIC ACID -- -
===================== Product Identification ===================== Product ID:HYDRIODIC ACID MSDS Date:Mar 07 1990 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:HYDRIODIC ACID CAS:10034-85-2 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: irritation (possibly severe), lung congestion LONG TERM EXPOSURE: digestive disorders SKIN CONTACT: SHORT TERM EXPOSURE: burns LONG TERM EXPOSURE: same as effects reported in short term exposure EYE CONTACT: SHORT TERM EXPOSURE: burns LONG TERM EXPOSURE: same as effects reported in short term exposure INGESTION: SHORT TERM EXPOSURE: burns LONG TERM EXPOSURE: same as effects reported in short term exposure Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing and shoes before reuse. Destroy contaminated shoes. EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. Give large amounts of water or milk. Allow vomiting to occur. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. NOTE TO PHYSICIAN: For inhalation, consider oxygen. Avoid gastric lavage or emesis. ===================== Fire Fighting Measures ===================== Extinguishing Media:carbon dioxide, regular dry chemical Large fires: Use regular foam or flood with fine water spray. Fire Fighting Procedures:Do not get water inside container. Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Keep unnecessary people away, isolate hazard area and deny entry. Use extinguishing agents appropriate for surrounding fire. Flood with fine water spray. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Consider downwind evacuation if material is leaking. Unusual Fire/Explosion Hazard:Negligible fire hazard. ================== Accidental Release Measures ================== Spill Release Procedures:Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water directly on material. Do not get water inside container. Keep unnecessary people away, isolate hazard area and deny entry. Small spills: Flood with water. Large spills: Dike for later disposal. Stay upwind and keep out of low areas. Ventilate closed spaces before entering. Evacuation radius: 150 feet. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with acid gas cartridge(s). Any chemical cartridge respirator with a full facepiece and acid gas cartridge(s). Any air-purifying respirator with a full facepiece and an acid gas canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health HYDRIODIC ACID: No occupational exposure limits established. ================== Physical/Chemical Properties ================== Boiling Pt:-31 F (-35 C) Melt/Freeze Pt:-58 F (-50 C) Vapor Pres:Not available Vapor Density:4.5 Spec Gravity:5.23 @ 25 C pH:acidic in solution Evaporation Rate & Reference:Not applicable Solubility in Water:70% @ 10 C Appearance and Odor:PHYSICAL STATE:gas COLOR:colorless ODOR:pungent odor Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stable at normal temperatures and pressure. Stability Condition to Avoid:Minimize contact with material. Avoid inhalation of material or combustion by-products. Containers may rupture or explode if exposed to heat. Hazardous Decomposition Products:Thermal decomposition products: iodinated compounds Thermal decomposition products: iodinated compounds Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:HYDRIODIC ACID: LOCAL EFFECTS: Corrosive: inhalation, skin, eye, ingestion ===================== Ecological Information ===================== Ecological:Not available ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Hydrogen iodide, anhydrous ID NUMBER: UN2197 HAZARD CLASS OR DIVISION: 2.3 LABELING REQUIREMENTS: Poison gas QUANTITY LIMITATIONS: PASSENGER AIRCRAFT OR RAILCAR: Forbidden CARGO AIRCRAFT ONLY: Forbidden ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: No REACTIVE: No SUDDEN RELEASE: Yes SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.