ASHLAND OIL INC -- TETRAHYDROFURAN -- 6810-00-982-8496
===================== Product Identification ===================== Product ID:TETRAHYDROFURAN MSDS Date:01/01/1987 FSC:6810 NIIN:00-982-8496 === Responsible Party === Company Name:ASHLAND OIL INC Address:1409 WINCHESTER AVE Box:391 City:ASHLAND State:KY ZIP:41114 Country:US Info Phone Num:606-329-3333 Emergency Phone Num:606-329-1133 CAGE:81355 === Contractor Identification === Company Name:ALBANY LABORATORIES CAGE:8D301 Company Name:ASHLAND INC Address:1409 WINCHESTER AVE Box:391 City:ASHLAND State:KY ZIP:41114 Country:US Phone:800-622-6846 CAGE:81355 ============= Composition/Information on Ingredients ============= Ingred Name:TETRAHYDROFURAN (SARA III) CAS:109-99-9 RTECS #:LU5950000 Fraction by Wt: >95% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/250 STEL ACGIH TLV:200 PPM/250STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Health Hazards Acute and Chronic:CONTACT WITH THE EYES CAUSES IRRITATION, BURNS. CONTACT WITH THE SKIN CAN CAUSE MODERATE IRRITATION, DEFATTING, DERMATITIS. EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY IRRITATION, D IZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE AND POSSIBLE UNCONSCIOUSNESS. INGEST: NAUSEA, IRRITATION, VOMITING. Explanation of Carcinogenicity:NOT SPECIFIED BY MANUFACTURER. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:6F,-14C Lower Limits:2 Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:MATERIAL IS HIGHLY VOLATILE AND READILY GIVES OFF VAPORS WHICH MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION TO A SOURCE OF IGNITION. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. CLEAN UP BY ABSORPTION ON AN INERT MATERIAL SUCH AS PAPER, VERMICULATE, SAND, CLAY, ETC. TRANSFER INTO APPROPRIATE CONTAINERS FOR DISPOSAL. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/ WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED. Protective Gloves:RESISTANT MATERIAL. Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:151F,66C Vapor Pres:143 Vapor Density:2.4 Spec Gravity:0.888 Evaporation Rate & Reference:8.0 (BUTYL ACETATE=1) Appearance and Odor:NOT SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES. CAN FORM EXPLOSIVE PEROXIDES UPON LONG STANDING IN AIR. Hazardous Decomposition Products:EXPLOSIVE PEROXIDES. Conditions to Avoid Polymerization:CAN OCCUR IN THE PRESENCE OF CATIONIC INITIATORS SUCH AS LEWIS ACIDS OR STRONG PROTON ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.