SPECTRUM CHEMICAL MFG. CORP. -- NICKEL SULFATE HEXAHYDRATE -- 6810-00-281-2684
===================== Product Identification ===================== Product ID:NICKEL SULFATE HEXAHYDRATE MSDS Date:06/23/1999 FSC:6810 NIIN:00-281-2684 Status Code:A === Responsible Party === Company Name:SPECTRUM CHEMICAL MFG. CORP. Address:14422 SOUTH SAN PEDRO STREET City:GARDENA State:CA ZIP:90248-2027 Country:US Info Phone Num:310-516-8000 Emergency Phone Num:800-424-9300 Preparer's Name:G.A.BINAS Chemtrec Ind/Phone:(800)424-9300 CAGE:63415 === Contractor Identification === Company Name:INDUSTRIAL CHEMICAL COMMODITIES INC Address:15944 DERWOOD RD Box:City:ROCKVILLE State:MD ZIP:20855 Country:US Phone:800-284-5279 Contract Num:SP0450-00-M-SF57 CAGE:1ELU0 Company Name:SPECTRUM LABORATORY PRODUCTS INC Address:14422 S SAN PEDRO ST Box:City:GARDENA State:CA ZIP:90248-2027 Country:US Phone:310-516-8000/FAX: 310-516-9843 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL SULFATE HEXAHYDRATE CAS:10101-97-0 RTECS #:QR9600000 = Wt:100. OSHA PEL:1 MG/M3 ACGIH TLV:0.1 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 RAT: 264 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: VERY HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT), OF EYE CONTACT (IRRITANT), OF INGESTION, OF INHALATION. INFLAMMATION OF THE EYE IS CHARACTERIZED BY REDNESS, WATERING, AND ITCHING. SKIN INFLA MMATION IS CHARACTERIZED BY ITCHING, SCALING, REDDENING, OR, OCCASSIONALLY, BLISTERING. CHRONIC: VERY HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT), OF EYE CONTACT (IRRITANT), OF INGESTION, OF INHALATI ON. REPEATED OR PROLONGED INHALATION OF DUST MAY LEAD TO CHRONIC RESPIRATORY IRRITATION. Explanation of Carcinogenicity:CARCINOGEN EFFECTS: CLASSIFIED A1 (CONFIRMED FOR HUMAN) BY ACGIH. 1(PROVEN FOR HUMAN) BY IARC, +(PROVEN) BY OSHA. CLASSIFIED 2 (REASONABLY ANTICIPATED) BY NTP. Effects of Overexposure:EYES: REDNESS, WATERING, AND ITCHING. SKIN: INFLAMMATION IS CHARACTERIZED BY ITCHING, SCALING, REDDENING, OR, OCCASSIONALLY, BLISTERING. IRRITANT. INHALATION: CHRONIC RESPIRATORY IRRITATION. ======================= First Aid Measures ======================= First Aid:EYE: REMOVE CONTACT LENSES. FLUSH EYES WITH WATER FOR 15 MINUTES, KEEPING EYELIDS OPEN. DO NOT USE EYE OINTMENT. GET MEDICAL ATTENTION. SKIN: WASH CONTAMINATED SKIN WITH WATER AND NON-ABRASIVE SOAP. CLEAN FOLDS, CREVICES, AND GROIN. COVERIRRITATED SKIN WITH EMOLLIENT. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SERIOUS SKIN CONTACT: WASH WITH DISINFECTANT SOAP AND COVER CONTAMINATED SKIN WIT H ANTI-BACTERIAL CREAM. SEEK MEDICAL ATTENTION. INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE MOUTH TO MOUTH RESUSCITATION. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET MEDICA L ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:N0N-FLAMMABLE Extinguishing Media:NON-FLAMMABLE. Unusual Fire/Explosion Hazard:RISKS OF EXPLOSION OF THE PRODUCT IN PRESENCE OF MECHANICAL IMPACT: NOT AVAILABLE. RISKS OF EXPLOSION OF THE PRODUCT IN PRESENCE OF STATIC DISCHARGE: NOT AVAILABLE. ================== Accidental Release Measures ================== Spill Release Procedures:USE APPROPRIATE TOOLS TO PUT SPILLED SOLID IN WASTE DISPOSAL CONTAINER. FINISH CLEANING BY SPREADING WATER ON CONTAMINATED SURFACE. DISPOSE OF ACCORDING TO LOCAL AND REGIONAL REQUIREMENTS. LARGE SPIL L: USE SHOVEL TO PUT MATERIAL INTO WASTE DISPOSAL CONTAINER. FINISH CLEANING BY SPREADING WATER ON CONTAMINATED SURFACE. ALLOW TO DRAIN THROUGH SANITARY SYSTEM. CHECK THAT EXPOSURE LEVEL IS BELOW TLV. ====================== Handling and Storage ====================== Handling and Storage Precautions:PRECAUTIONS: KEEP LOCKED UP. DO NOT INGEST. DO NOT BREATHE DUST. IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT. IF INGESTED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THE CON TAINER OR THE LABEL. AVOID CONTACT WITH SKIN OR EYES. Other Precautions:CARCINOGENIC, TERATOGENIC OR MUTAGENIC MATERIALS SHOULD BE STORED IN A SEPARATE LOCKED SAFETY STORAGE CABINET OR ROOM. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:BE SURE TO USE AN APPROVED/CERTIFIED RESPIRATOR OR EQUIVALENT OR DUST RESPIRATOR IF ADEQUATE. FOR LARGE SPILLS, WEAR A SELF-CONTAINED BREATHING APPARATUS TO AVOID INHALATION OF PRODUCT. Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. Protective Gloves:YES Eye Protection:SPLASH GOGGLES. Other Protective Equipment:LAB COAT, DUST RESPIRATOR, GLOVES. FOR LARGE SPILLS WEAR SPLASH GOGGLES, FULL SUIT, DUST RESPIRATOR, BOOTS, GLOVES. A SELF-CONTAINED BREATHING APPARATUS TO AVOID INHALATION OF PRODUCT. Work Hygienic Practices:SUGGESTED PROTECTIVE CLOTHING MIGHT NOT BE SUFFICIENT, CONSULT A SPECIALIST BEFORE HANDLING THIS PRODUCT. Supplemental Safety and Health CATALOG NUMBER: N1069 AND N1070. HCC= T7 PICKED OVER T6 BASED ON TABLE B-3, ORDER OF ASSIGNMENT PREFERENCE SING 49 CFR AS A BASIS. ================== Physical/Chemical Properties ================== HCC:T7 Vapor Density:9.1 Spec Gravity:2.03 Solubility in Water:SOLUBLE Appearance and Odor:SOLID. (CRYSTALINE SOLID); ODORLESS. EMERALD-GREEN COLOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT AVAILABLE Stability Condition to Avoid:NOT AVAILABLE Hazardous Decomposition Products:NOT AVAILABLE =================== Toxicological Information =================== Toxicological Information:ROUTES OF ENTRY: EYE CONTACT, INHALATION, INGESTION. ANIMAL TOXICITY: ACUTE ORAL TOXICITY (LD50) RAT : 264 MG/KG. CHRONIC EFFECTS ON HUMANS: CARCINOGENIC EFFECTS: CLASSED A1 (CONFIRMED FOR HUMAN) BY ACGIH; CLASSIFIED 1 (PROVEN FOR HUMAN) BY IARC; CLASSIFIED + (PROVEN) BY OSHA; CLASSIFIED 2 (REASONABLY ANTICIPATED) BY NTP. OTHER TOXIC EFFECTS ON HUMANS: VERY HAZARDOUS IN CASE OF SKIN CONTACT (IRRI TANT), OF INGESTION, OF INHALATION. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: NOT AVAILABLE. BODS AND COD: NOT AVAILABLE. PRODUCTS OF BIODEGRADATION: POSSIBLY HAZARDOUS SHORT TERM DEGRADATION PRODUCTS ARE NOT LIKELY. HOWEVER, LONG TERM DEGRADATION PRODUCTS MAY ARIS E. TOXICITY OF THE PRODUCTS OF BIODEGRADATION: THE PRODUCTS OF DEGRADATION ARE MORE TOXIC. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLE TO PROCESS IF POSSIBLE. CONSULT YOUR LOCAL OR REGIONAL AUTHORITIES. =================== MSDS Transport Information =================== Transport Information:DOT CLASSIFICATION: NOT A DOT CONTROLLED MATERIAL (UNITED STATES). HOWEVER, PRODUCT MEETS THE DEFINITION OF A D.O.T. CLASS 9, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID , N.O.S. UN 3077, PG I I I. TH E CTDF FOR THIS PRODUCT ALSO SPECIFIES THIS CLASS 9 SHIPING CLASS. ===================== Regulatory Information ===================== SARA Title III Information:SARA 313 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING: NICKEL SULFATE HEXAHYDRATE. CERCLA: HAZARDOUS SUBSTANCES: NICKEL SULFATE HEXAHYDRATE. Federal Regulatory Information:TSCA 8(B) INVENTORY: NICKEL SULFATE HEXAHYDRATE. OTHER REGULATIONS: OSHA: HAZARDOUS BY DEFINTION OF HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). State Regulatory Information:CALIFORNIA PROP 65: THIS PRODUCT CONTAINS THE FOLLOWING INGREDIENTS FOR WHICH THE STATE OF CALIFORNIA HAS FOUND TO CAUSE CANCER, BIRTH DEFECTS, OR OTHER REPRODUCTIVE HARM, WHICH WOULD REQUIRE A WARNI NG UNDER THE STATUTE: NICKEL SUFATE HEXAHYDRATE. ALSO THIS PRODUCT CONTAINS THE FOLLOWING INGREDIENTS FOR WHICH THE STATE OF CALIFORNIA HAS FOUND TO CAUSE CANCER WHICH WOULD REQUIRE A WARNING UNDER TH E STATUTE: NICKEL SULFATE HEXAHYDRATE. PENNSYLVANIA RTK: NICKEL SULFATE HEXAHYDRATE. MASSACHUSETTS R TK: NICKEL SULFATE HEXAHYDRATE. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.