CABOT CORP -- BERYLLIUM COPPER CASTING ALLOYS, CU-4BE (MA -- 9525-00N035527
===================== Product Identification ===================== Product ID:BERYLLIUM COPPER CASTING ALLOYS, CU-4BE (MA MSDS Date:11/01/1985 FSC:9525 NIIN:00N035527 === Responsible Party === Company Name:CABOT CORP Box:1296 City:READING State:PA ZIP:19603 Country:US Info Phone Num:215-921-5000;215-921-5002 Emergency Phone Num:215-921-5000;800-424-9300(CHEMTREC) Preparer's Name:W.J. HETRICK CAGE:0VZP9 === Contractor Identification === Company Name:CABOT CORP Address:157 CONCORD RD Box:188 City:BILLERICA State:MA ZIP:01821-5000 Country:US Phone:508-670-6191 CAGE:0VZP9 Company Name:CABOT CORP ALUMINUM MASTER ALLOY BUSINESS UNIT Address:601 PENN ST Box:1296 City:READING State:PA ZIP:19601 Country:US Phone:215-921-5000,CHEMTREC 800-424-9300 CAGE:70787 ============= Composition/Information on Ingredients ============= Ingred Name:ING 5:TO FURTHER RISK IF HANDLING AND USE OF MATERIAL CAUSES EXCESSIVE EXPOSURE. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:EYE:PARTICULATE METAL (DUST, FUME OR POWDER) MAY BE DANGEROUS TO EYE & SURROUNDING TISS. AIRBORNE(ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:PARTICULATE (CHIPS, DUST OR POWDER) IS ALWAYS POTNTL PROBLEM AS WELL AS INSERTING FINGERS INTO EYE SOCKET IF(ING 9 RTECS #:9999999ZZ Ingred Name:ING 8:THE HAND/CLTHG IS CONTAM W/METAL PARTICULATE. ACUTE:METAL DUST & FUMES OF INGREDS CAN CAUSE IRRIT TO SKIN,(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:EYE AND MUCUS MEMBRANE. CONTACT COPPER MAY CAUSE ALLERGIC SKIN REACTIONS. AS DUST, POWDER, FUME, (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:EXPOS WHICH ABRADES SKIN CAN CAUSE IRRIT & DERM. INJURY TO EYE IS GENERALLY RSLT OF PARTICULATE IRRIT (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:OR MECH INJURY TO CORNEA OR CONJUNCTIVA BY DUST/PARTICULATE. EXCESS INHAL OF COPPER & NICKEL CAN CAUSE (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:RESP IRRIT, COUGH, BRONCH, CHILLS, "FUME FEVER", & ASTHMA-LIKE SYMPS.CHRONIC:RESP DISEASE W/SYMPS RANGING(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:FROM SHORTNESS OF BREATH & COUGH TO PERM DISABILITY DUE TO LOSS OF LUNG FUNCTION, FIBROSIS OR SUBSEQUENT (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:EFTS ON HEART MAY BE CAUSED BY EXCESS EXPOS TO DUST OR FUMES CNTNG BERYLLIUM. CENTRAL NERVOUS SYSTEM (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: BERYLLIUM HAS BEEN LINKED TO NASAL, BRONCHIAL & LUNG CANCERS. INHALATION OF BERYLLIUM IN EXCESS (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: CONCENTRATION CAN CAUSE A SERIOUS LUNG DISEASE CALLED BERYLLIOSIS. CHRONIC HEALTH EFFECTS SPECIFIC TO (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: ELEMENT(S) MAY BE DIFFCULT TO DETECT DUE TO NUMEROUS ELEMENTAL CONSTITUENTS IN ALLOY. RTECS #:9999999ZZ Ingred Name:CARCINOGENICITY: SIXTH ANNUAL REPORT ON CARCINOGEN, 1991 SUMMARY) . RTECS #:9999999ZZ Ingred Name:BERYLLIUM (SARA III) CAS:7440-41-7 RTECS #:DS1750000 Fraction by Wt: 4% OSHA PEL:2 UG/M3 ACGIH TLV:0.002PPM; A2; 9293 Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: BALANCE OSHA PEL:0.1MG/M3 FUME;1 DUST ACGIH TLV:0.2MG/M3 FUME;1 DUST EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MED CNDTNS:CNDTNS SUCH AS ASTHMA, EMPHYSEMA, CHRONIC BRONCH, ETC. MAY INCUR FURTHER DISABILITY IF EXCESS CONC (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:OF DUST/FUME ARE INHALED. IF PRIOR DMG OR DISEASE TO NEUROLOGIC (NERV), CIRCULATORY, HEMATOLOGIC (BLOOD) OR(ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:RENAL (KIDNEY) SYS HAS OCCURED, PROPER SCREENING OR EXAMS SHOULD BE CONDUCTED ON INDIV WHO MAY BE EXPOSED (ING 6) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHAL:INHAL OF METAL DUST, FUME OR POWDER MAY RSLT FROM MELTING, DROSS HNDLG, CASTING, WELDING, GRINDING, CRUSHING OR SIMILAR OPERS WHICH GENERATE AIRBORNE METAL PARTICULATE DURING USE OF MATL. INGEST :HAND, CLTHG, FOOD & DRINK CNTCT W/METAL DUST, FUME OR POWDER CAN CAUSE INGEST OF PARTICULATE DURING (EFTS OF OVEREXP) Explanation of Carcinogenicity:BERYLLIUM:POSS CARC TO HUM (GROUP 2A,IARC MONOGRAPH,VOL 7,PAGE 127,1987). ANTICIPATED TO BE CARC (GROUP 2, NTP (ING 19) Effects of Overexposure:HEALTH HAZARD: HAND TO MOUTH ACTIVITIES SUCH AS EATING, DRINKING, SMOKING, NAIL BITING, ETC. SKIN: IN FORM OF METAL DUST POWDER, SKIN CONTACT OR ABRASION MAY ALSO CAUSE IRRITITATION OR DERMATITIS. (IN G 7) Medical Cond Aggravated by Exposure:INDIV WHO MAY HAVE HAD ALLERG RXN OR SENSIT TO METALS SUCH AS CHROME & COPPER MAY ENCOUNTER SKIN RASH/DERM IF SKIN CNTCT W/PROD OCCURS. PERS W/IMPAIRED PULM FUNCTION, AIRWAY DISEASES & (ING 3) ======================= First Aid Measures ======================= First Aid:INHAL:BRTHG DFCLTY CAUSED BY DUST/FUME REQS REMOVAL TO FRESH AIR. IF BRTHG STOPPED, GIVE ARTF RESP & GET MD IMMED. INGEST:HAVE AFFECTED PERS DRINK LRG QTYS OF WATER & ATTEMPT TO INDUCE VOMIT IF CONSCI OUS. GET MD IMMED. SKIN:CUTS/ABRASIONS CAN BE TREATED BY STANDARD FIRST AID. SKIN CONTAM W/DUST/POWDER CAN BE REMOVED BY WASHING W/SOAP & WATER. IF IRRIT PERSISTS GET MD. EYE:FLUSH W/COPIOUS (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:USE EXTING MEDIA APPROP TO SURROUNDING FIRE. TO EXTING METAL POWDER FIRE USE DRY SAND, DRY GRAPHITE OR OTHER (SUPDAT) Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE EQUIPMENT . IF MATERIAL IS REDUCED TO POWDER FORM, CAUTION MUST BE USED TO PREVENT FIRE OR EXPLOSION. Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE ASSOCIATED WITH THIS MATERIAL. ================== Accidental Release Measures ================== Spill Release Procedures:IN SOLID FORM MATL POSES NO SPECIAL CLEAN-UP PROBLEMS. IF MATL IS IN POWDER/DUST FORM, CLEAN-UP SHOULD BE CONDUCTED W/VACUUM SYS UTILIZING HIGH EFFICIENCY PARTICULATE AIR FILTRATION SYS. CAUTION SHOUL D BE TAKEN TO MIN AIRBORNE GEN OF POWDER (SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE METAL AND METAL POWDER IN DRY AREA. DO NOT STORE ADJACENT TO MINERAL ACIDS. FINE METAL POWDERS SHOULD BE KEPT AWAY FROM FLAMES & IGNIT SOURCES. Other Precautions:PRODUCT MUST BE HANDLED ACCORDINGLY TO THE SIZE, SHAPE AND QUANTITY OF MATERIAL INVOLVED. SOLID METAL MAY REQ USE OF HOISTS, CRANES, ETC. POWDERS SHOULD BE MOVED OR TRANSPORTED TO MINIMIZE SPILL OR RE LEASE POTENTIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS AS SPECIFIED BY INDUSTRIAL HYGIENIST OR QUALIFIED SAFETY PROFESSIONAL. LUNG FUNCTION TESTS ARE RECOMMENDED FOR USERS OF NEGATIVE PRESSURE DEVICES. Ventilation:LOCAL EXHAUST VENTILATION SHOULD BE USED TO CONTROL EXPOSURE TO AIRBORNE DUST AND FUME WHENEVER POSSIBLE. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:UNIFORMS, DISPOSABLE COVERALLS, SAFETY SHOES, ETC. MAY BE REQUIRED DURING METAL HANDLING OPERATIONS AS APPROPRIATE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXTING MEDIA: CLASS "D" FIRE EXTING POWDER. FIRST AID PROC:AMTS OF CLEAN WATER FOR AT LEAST 15 MINS. IF IRRIT PERSISTS GET MD. CNTCT LENSES SHOULD NOT BE WORN WHEN WORKING WITH METAL DUSTS & POWDERS. SPILL PROC:OR DUST & AVOID CONTAMINATION OF AIR & WATER. PROPERLY LABEL ALL MATLS COLLECTED IN WASTE CONTAINER. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:NONE Appearance and Odor:SOLID, BRASS COLOR, NO ODOR Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/MINERAL ACIDS/OXIDIZING AGENTS WHICH MAY GENERATE HYDROGEN GAS; EVOLUTION OF HYDROGEN MAY BE EXPLO HAZ. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:VARIOUS ELEMENTAL METALS & METAL OXIDES MAY BE GENERATED FRM MELTING OR DROSS HANDLING OPERATIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PRIOR TO DISP CONSIDER IF MATL HAS RECOVERY VALUE. STATE/FED REGS MAY REQ SPECIFIC LABELING, PACKING, STORAGE, TRANSPORTATION, & DISP PROC. CNTCT ENVIRON ENGINEER/CONSULTANT FAMILIAR W/WASTE DISP REGS . DISP MUST BE I/A/W LOC, STATE & FED REGS . 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