MALLINCKRODT BAKER INC -- PETROLEUM ETHER, 9269  -- 6810-00N087519
<pre>=====================  Product Identification  =====================

Product ID:PETROLEUM ETHER, 9269
MSDS Date:07/23/1997
FSC:6810
NIIN:00N087519
=== Responsible Party ===
Company Name:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC)
CAGE:HO851
=== Contractor Identification ===
Company Name:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:HO851
Company Name:MALLINCKRODT BAKER,  INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829

=============  Composition/Information on Ingredients  =============

Ingred Name:VM&P NAPHTHA (LIGROINE)
CAS:8032-32-4
RTECS #:OI6180000
Fraction by Wt: 90-100%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM

Ingred Name:SUPDAT: WITH STRONG OXIDIZERS MAY CAUSE FIRE.
RTECS #:9999999ZZ

Ingred Name:CNDTNS TO AVOID: SOURCES, SUNLIGHT AND INCOMPATIBLES.
RTECS #:9999999ZZ

Ingred Name:EFTS OF OVEREXP:OVEREXP MAY CAUSE DRYING & CRACKING OF SKIN
    & ASSOC DERM. NO CHRONIC SYSTEMIC EFTS HAVE BEEN (ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4: RPTD FROM WIDESPREAD INDUSTRIAL USE.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: CALL PHYS, IMMED. WASH CLTHG BEFORE REUSE.
    EYE CONT: IMMED FLUSH W/PLENTY OF WATER FOR @ LST (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6: 15 MINS, LIFTING LOWER & UPPER EYELIDS OCCASNLY. GET
    MED ATTN IMMED. NOTE TO PHYS: MONITOR ALL SIGNIFICANT(ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: INHALATIONS & INGESTIONS FOR SIGNS OF TOX &
    DEVELOPMENT OF PULM EDEMA FOR @ LST 6 HRS. LABEL FIRST AID: (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: ASPIR HAZ. IF SWALLOWED, VOMIT MAY OCCUR SPONT, BUT
    DO NOT INDUCE. IF VOMIT OCCURS, KEEP HEAD BELOW HIPS (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: TO PVNT ASPIR INTO LUNGS. NEVER GIVE ANYTHING BY
    MOUTH TO UNCON PERSON. CALL PHYS IMMED. IF INHALED, (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP.
    IF BRTHG IS DFCLT, GIVE OXYG. IN CASE OF CONT, IMMED (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: FLUSH EYES/SKIN W/PLENTY OF WATER FOR @ LST 15
    MINS. IN CALL CASES CALL A PHYSICIAN.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: APPROP CNTNRS/ABSORB W/INERT MATL (E.G.,
    VERMICULITE, DRY SAND, EARTH), & PLACE IN CHEM WASTE CNTNR.(ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: DO NOT USE COMBUST MATLS, SUCH AS SAW DUST. DO NOT
    FLUSH TO SEWER! IF LEAK/SPILL HAS NOT INGITED, USE (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: WATER SPRAY TO DISPERSE VAPS, TO PROTECT PERS
    ATTEMPTING TO STOP LEAK, & TO FLUSH SPILLS AWAY FROM (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: EXPOS. J.T. BAKER SOLUSORB(TM) SOLV ABSORB IS REC
    FOR SPILLS OF PROD. ECOLOGICAL INFO: WHEN RELEASED (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: INTO SOIL, THIS MATL IS EXPECTED TO READILY
    BIODEGRADE. FOR MORE SPECIFIC INFO CONT NEHC .
RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH: DIFFER FROM FED DISP REGS. DISPOSE OF
    CNTNR & UNUSED CONTENTS I/A/W FEDERAL, STATE & LOC REQUIREMENTS.
RTECS #:9999999ZZ

Ingred Name:OTHER PREC: ISOLATE FROM INCOMPAT SUSTANCES. CNTNRS OF MATL
    MAY BE HAZ WHEN EMPTY SINCE THEY RETAIN PROD (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19: RESIDUES (VAPS, LIQ); OBSERVE ALL WARNINGS & PREC
    LISTED FOR PROD. FOR MORE SPECIFIC INFO CONT NEHC .
RTECS #:9999999ZZ

Ingred Name:RESP PROT: VAP RESP MAY BE WORN UP TO 50 TIMES EXPOS
    LIMIT/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/ (ING 22)
RTECS #:9999999ZZ

Ingred Name:ING 21:RESP SUPPLIER, WHICHEVER IS LOWEST. FOR
    EMER/INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE NIOSH
    APPRVD(ING 23)
RTECS #:9999999ZZ

Ingred Name:ING 22: FULL-FACE PIECE POS-PRESS, AIR-SUPPLIED RESP.
    WARNING: NIOSH APPRVD AIR-PURIFYING RESPS DO NOT PROTECT (ING 24)
RTECS #:9999999ZZ

Ingred Name:ING 23: WORKERS IN OXYGEN -DEFICIENT ATMOSPHERES.
RTECS #:9999999ZZ

Ingred Name:VENT: PREFERRED BECAUSE IT CAN CTL EMISSIONS OF CONTAMINANT
    AT ITS SOURCE, PVNTG DISPERSION OF IT IN GEN WORK AREA.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE SYMPS OF
    INTOXICATION & PERIPHERAL NERVE DISORDERS & CNS DEPRESS. SYMPS OF
    OVEREXP INCL LOSS OF APPETITE, MUSCLE WEAK, IMPAIRMENT OF MOTOR
    ACTION, DIZZ & DROW. MAY ALSO CAUSE T HROAT IRRIT. INGEST: LOC
    IRRIT W/BURNING SENSATION IN MOUTH, ESOPHAGUS, & STOM. VOMIT,
    BLURRED VISION, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: & DIARR MAY ALSO OCCUR. CASES OF CHEM
    PNEUM HAVE BEEN RPTD FROM INGEST OF SUBSTANCE. NERV SYS DISORDERS
    PARALLELING THOSE FROM INHAL EXPOS MAY ALSO OCCUR. SKIN CONT: MAY
    CAUSE IRRIT. LIQ ACT S AS DEFAT AGENT ON SKIN. EYE CONT: VAPS MAY
    CAUSE IRRIT. SPLASHES MAY CAUSE REDNESS & PAIN. CHRONIC: PRLNGD
    (ING 4)
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
    DISORDERS/EYE PROBLEMS/IMPAIRED LIVER, KIDNEY/RESPIRATORY FUNCTION
    MAY BE MORE SUSCEPTIBLE TO EFFECTS OF THE SUBSTANCE.

=======================  First Aid Measures  =======================

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
    BRTHG IS DFCLT, GIVE OXYG. CALL PHYS. INGEST: ASPIR HAZ. IF
    SWALLOWED, VOMIT MAY OCCUR SPONT, BUT DO NOT INDUCE. IF VOMIT
    OCCURS, KEEP HEAD  BELOW HIPS TO PVNT ASPIR INTO LUNGS. NEVER GIVE
    ANYTHING BY MOUTH TO UNCON PERSON. CALL PHYS IMMED. SKIN: IMMED
    FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS WHILE REMOVING CONTAMD
    CLTHG & SHOES. (ING 6)

=====================  Fire Fighting Measures  =====================

Flash Point Method:CC
Flash Point:0F,-18C
Lower Limits:1.1%
Upper Limits:5.9%
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER MAY BE
    INEFTIVE. DO NOT ALLOW WATER RUNOFF TO ENTER SEWERS OR WATERWAYS.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER
    SPRAY MAY BE USED TO KEEP FIRE EXPOS CNTNRS COOL. IF LEAK/SPILL HAS
    NOT IGNITED, USE WATER SPRAY TO (SUPDAT)
Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAP-AIR MIX ARE EXPLO
    W/IN FLAMM LIMS. SEALED CNTNRS MAY RUPTURE WHEN HEATED. SENSITIVE
    TO STATIC DISCHARGE. VALUES LISTED ARE FOR (SUPDAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENTILATE AREA OF LEAK/SPILL. REMOVE ALL
    SOURCES OF IGNIT. WEAR APPROP PERSONAL PROT EQUIP AS SPECIFIED.
    ISOLATE HAZ AREA. KEEP UNNEC & UNPROTECTED FROM ENTERING. CNTN &
    RECOVER LIQ WHEN POSS. USE NON -SPARKING TOOLS & EQUIP. COLLECT LIQ
    INAN(ING 13)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DMG. STORE IN
    COOL, DRY WELL-VENTILATED LOCATIONS, AWAY FROM ANY AREA WHERE FIRE
    HAZ MAY BE ACUTE.
Other Precautions:OUTSIDE/DETACHED STOR IS PREFERRED. SEPARATE FROM
    INCOMPAT. CNTNRS SHOULD BE BONDED & GROUNDED FOR TRANSFER TO AVOID
    STATIC SPKS. STOR & USE AREAS SHOULD BE NO SMKNG AREAS. USE NON-SPK
    TYPE TOOLS & EQ UIP, INCL EXPLO PROOF VENT. (ING 19)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF EXPOS LIMIT IS EXCEEDED, NIOSH APPRVD
    HALF-FACE ORG VAP RESP MAY BE WORN FOR UP TO 10 TIMES EXPOS
    LIMIT/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP
    SUPPLIER, WHICHEVER IS LOWEST. A NIOS H APPRVD FULL-FACE PIECE ORG
    (ING 21)
Ventilation:SYS OF LOC &/OR GEN EXHAUST IS REC TO KEEP EMPLOYEE EXPOS
    BELOW AIRBORNE EXPOS LIMITS. LOC EXHAUST VENT IS GEN (ING 25)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
    IMPERVIOUS PROT CLTHG, BOOTS, LAB COAT/OVERALLS TO PVNT CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRE FIGHT PROC: DISPERSE VAPS, TO PROTECT PERSONNEL ATTEMPTING TO STOP
    LEAK, & TO FLUSH SPILLS AWAY FROM EXPOSURES. VAPS CAN FLOW ALONG
    SURFS TO DISTANT IGNIT SOURCE & FLASH BACK. EXPLO HAZ: PETRO ET
    HER. EXTREMELY FLAMM LIQ & VAP! VAP MAYCAUSE FLASH FIRE. DANGEROUS
    FIRE HAZ WHEN EXPOS TO HEAT/FLAME. CONT (ING 2)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:>68F,>20C
Melt/Freeze Pt:M.P/F.P Text:<-99F,<-73C
Vapor Pres:40 @ 20C
Vapor Density:2.5
Spec Gravity:0.60-0.75
Evaporation Rate &amp; Reference:10 (BUAC =1)
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID. GASOLINE OR KEROSENE ODOR.
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS. WILL ATTACK SOME FORMS OF PLASTICS, RUBBER AND
    COATINGS.
Stability Condition to Avoid:STABLE UNDER ORDINARY CNDTNS OF USE &
    STOR. HEAT & SUNLIGHT CAN CONTRIBUTE TO INSTABILITY. HEAT, FLAME,
    IGNIT (ING 3)
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY
    FORM WHEN HEATED TO DECOMPOSITION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
    SHOULD BE HNDLD AS HAZ WASTE & SENT TO RCRA APPRVD INCIN/DISPOSED
    IN RCRA APPRVD WASTE FACILITY. PROCESSING, USE/CONTAM OF PROD MAY
    CHANGE WASTE MANAGEM ENT OPTIONS. STATE & LOC DISP REGS MAY (ING
    18)

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